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Catalytic enantioselective conjugate allylation of unsaturated methylidene ketones.

ABSTRACT: The use of unsaturated methylidene ketones in catalytic conjugate allylations allows a significant expansion in substrate scope and, with appropriate chiral ligands, occurs in a highly enantioselective fashion.

SUBMITTER: Brozek LA 

PROVIDER: S-EPMC3065356 | biostudies-literature | 2011 Mar

REPOSITORIES: biostudies-literature

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Catalytic enantioselective conjugate allylation of unsaturated methylidene ketones.

Brozek Laura A LA   Sieber Joshua D JD   Morken James P JP  

Organic letters 20110202 5

The use of unsaturated methylidene ketones in catalytic conjugate allylations allows a significant expansion in substrate scope and, with appropriate chiral ligands, occurs in a highly enantioselective fashion. ...[more]

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