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N-(3-Chloro-phen-yl)-N'-(2-methyl-phenyl)succinamide monohydrate.

ABSTRACT: In the title compound, C(17)H(17)ClN(2)O(2)·H(2)O, the dihedral angles formed by the aromatic rings of the chloro-benzene and methyl-benzene groups with the mean planes of the attached NH-C(O)-CH(2) fragments are 9.4?(4) and 62.9?(2)°, respectively. In the crystal, mol-ecules are packed into layers parallel to the bc plane by O-H?O and N-H?O hydrogen-bond inter-actions.

SUBMITTER: Saraswathi BS

PROVIDER: S-EPMC3089173 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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N-(3-Chloro-phen-yl)-N'-(2-methyl-phenyl)succinamide monohydrate.

Saraswathi B S BS Foro Sabine S Gowda B Thimme BT

Acta crystallographica. Section E, Structure reports online 20110429 Pt 5

In the title compound, C(17)H(17)ClN(2)O(2)·H(2)O, the dihedral angles formed by the aromatic rings of the chloro-benzene and methyl-benzene groups with the mean planes of the attached NH-C(O)-CH(2) fragments are 9.4 (4) and 62.9 (2)°, respectively. In the crystal, mol-ecules are packed into layers parallel to the bc plane by O-H⋯O and N-H⋯O hydrogen-bond inter-actions. ...[more]

PMID: 21754521

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N-(4-Chloro-phen-yl)-N'-(3-methyl-phen-yl)succinamide monohydrate.

Project description:In the title hydrate, C(17)H(17)ClN(2)O(2)·H(2)O, the dihedral angles formed by the aromatic rings of the chloro-benzene and methyl-benzene groups with the mean planes of their attached NH-C(O)-CH(2) fragments are 16.6?(2) and 22.8?(2)°, respectively. In the crystal, O-H?O and N-H?O hydrogen bonds link the components into a two-dimensional network parallel to the ab plane.

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N-(2-Chloro-phen-yl)-N'-(2-methyl-phen-yl)succinamide.

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N-(3-Chloro-phen-yl)-N'-(3-methyl-phen-yl)succinamide.

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3-(4-Chloro-phen-yl)-1-[(E)-1-(4-chloro-phen-yl)-2-(4-methyl-phenyl-sulfan-yl)ethen-yl]-4-(4-methyl-phenyl-sulfan-yl)-1H-pyrazole.

Project description:In the title compound, C(31)H(24)Cl(2)N(2)S(2), the pyrazole ring adopts planar conformation with a maximum deviation of 0.002?(2)?Å. The chloro-phenyl rings are twisted out of the plane of the pyrazole ring by 75.1?(1) and 39.5?(1)°. The crystal packing is controlled by weak intermolecular C-H?? interactions.

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N,N-Bis(4-chloro-phenyl-sulfon-yl)succinamide dihydrate.

Project description:The asymmetric unit of the title compound, C(16)H(14)Cl(2)N(2)O(6)S(2)·2H(2)O, contains one half-mol-ecule of N,N-bis-(4-chloro-phenyl-sulfon-yl)succinamide, with a centre of symmetry at the mid-point of the central C-C bond, and one water mol-ecule. The succinamide mol-ecules are not directly connected via hydrogen bonds, but by hydrogen bonds via the water mol-ecules.

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N,N'-Bis(3-methyl-phen-yl)succinamide dihydrate.

Project description:The asymmetric unit of the title compound, C(18)H(20)N(2)O(2)·2H(2)O, contains half a mol-ecule with a center of symmetry at the mid-point of the central C-C bond. The N-H bonds in the amide fragments are anti to the meta-methyl groups in the adjacent benzene rings. The dihedral angle between the benzene ring and the NH-C(O)-CH(2) segment in the two halves of the mol-ecule is 5.6?(4)°. In the crystal, the packing of mol-ecules through O-H?O and N-H?O hydrogen-bonding inter-actions leads to the formation of layers parallel to the bc plane. The methyl group is disordered with respect to the 3- and 5-positions of the benzene ring, with site-occupation factors of 0.910?(8) and 0.090?(8).

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2-[2-Chloro-5-(trifluoro-methyl)-phen-yl]hexa-hydro-pyrimidine monohydrate.

Project description:The mol-ecule of the title compound, C(11)H(12)ClF(3)N(2)·H(2)O, is a substituted hexa-hydro-pyrimidine. There are two crystallographically independent mol-ecules (A and B) and two water mol-ecules in the asymmetric unit of the title compound. Inter-molecular C-H?Cl (× 2), C-H?F, and C-H?N (× 2) hydrogen bonds generate S(5) ring motifs. The dihedral angle between the two benzene rings is 8.17?(11)°. The F atoms in mol-ecule B are disordered over four positions with refined site-occupancies of ca 0.35/0.19/0.29/0.17 for the four components. In the crystal structure, mol-ecules are arranged into one-dimensional extended chains along the c axis and are further stacked along the a axis by directed four-membered O-H?O-H inter-actions, forming two-dimensional networks parallel to the ac plane. The short distances between the centroids of the benzene rings (3.8002-3.8327?Å) indicate the existence of ?-? inter-actions. In addition, the crystal structure is further stabilized by N-H?O, O-H?N (× 4), N-H?Cl and C-H?O (× 2) hydrogen-bonding inter-actions.

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