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(E)-1-(2,4-Dinitro-phen-yl)-2-[1-(2-nitro-phen-yl)ethyl-idene]hydrazine.

ABSTRACT: The title compound, C(14)H(11)N(5)O(6), was obtained from the condensation reaction of 2,4-dinitro-phenyl-hydrazine and 2-nitro-acetophenone. The mol-ecule displays an E conformation about the C=N double bond and an intra-molecular N-H?O hydrogen bond generates an S(6) ring motif. The dihedral angle between the benzene rings is 7.84?(6)°. In the crystal, mol-ecules are linked by C-H?O hydrogen bonds and ?-? stacking inter-actions [centroid-centroid distance = 3.6447?(8)?Å] into a three-dimensional network.

SUBMITTER: Nilwanna B

PROVIDER: S-EPMC3247472 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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(E)-1-(2,4-Dinitro-phen-yl)-2-[1-(2-nitro-phen-yl)ethyl-idene]hydrazine.

Nilwanna Boonlerd B Chantrapromma Suchada S Jansrisewangwong Patcharaporn P Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20111029 Pt 11

The title compound, C(14)H(11)N(5)O(6), was obtained from the condensation reaction of 2,4-dinitro-phenyl-hydrazine and 2-nitro-acetophenone. The mol-ecule displays an E conformation about the C=N double bond and an intra-molecular N-H⋯O hydrogen bond generates an S(6) ring motif. The dihedral angle between the benzene rings is 7.84 (6)°. In the crystal, mol-ecules are linked by C-H⋯O hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 3.6447 (8) Å] into a three-dimension ...[more]

PMID: 22220090

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