Unknown

Dataset Information

0

(3R,4S)-3,4-Isopropyl-idenedioxy-3,4-dihydro-2H-pyrrole 1-oxide.

ABSTRACT: The title compound C(7)H(11)NO(3) was prepared by intra-molecular nucleophilic displacement of 2,3-O-iso-propyl-idene-d-erythronolactol. There are two mol-ecules in the asymmetric unit, which are related by a pseudo-inversion centre. The crystal structure determination confirms unequivocally the configuration of the chiral centres as 3S,4R. In the crystal structure, inter-molecular C-H?O inter-actions link the mol-ecules (into infinite zigzag chains along the a axis.

SUBMITTER: Flores MF 

PROVIDER: S-EPMC3089370 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

(3R,4S)-3,4-Isopropyl-idenedioxy-3,4-dihydro-2H-pyrrole 1-oxide.

Flores Mari Fe MF   Garcia Pilar P   M Garrido Narciso N   Sanz Francisca F   Diez David D  

Acta crystallographica. Section E, Structure reports online 20110413 Pt 5

The title compound C(7)H(11)NO(3) was prepared by intra-molecular nucleophilic displacement of 2,3-O-iso-propyl-idene-d-erythronolactol. There are two mol-ecules in the asymmetric unit, which are related by a pseudo-inversion centre. The crystal structure determination confirms unequivocally the configuration of the chiral centres as 3S,4R. In the crystal structure, inter-molecular C-H⋯O inter-actions link the mol-ecules (into infinite zigzag chains along the a axis. ...[more]

Similar Datasets

Unknown (3R,4S)-3,4-Isopropylidenedioxy-5-phenylsulfonylmethyl-3,4-dihydro-2H-pyrrole 1-oxide.
| S-EPMC3089343 | biostudies-literature
Unknown 5-(3-Chloro-phen-yl)-2-phenyl-3,4-dihydro-2H-pyrrole.
| S-EPMC3009276 | biostudies-other
Unknown Crystal structure of [(2R,3R,4S)-3,4-bis(acet-yloxy)-5-iodo-3,4-di-hydro-2H-pyran-2-yl]methyl acetate.
| S-EPMC4331918 | biostudies-literature
Unknown tert-Butyl 4-isopropyl-2-oxo-6-phenyl-3,4-dihydro-2H-pyran-3-carboxyl-ate.
| S-EPMC2979271 | biostudies-literature
Unknown 2,2,7-Trichloro-3,4-dihydro-naphthalen-1(2H)-one.
| S-EPMC2969904 | biostudies-literature
Unknown 3,4-Dihydro-1,4-benzothia-zepin-5(2H)-one.
| S-EPMC2915184 | biostudies-literature
Unknown The Enantiomeric Discrimination of 5-Hexyl-2-methyl-3,4-dihydro-2H-pyrrole by Sulfobutyl ether-β-cyclodextrin: A Case Study.
| S-EPMC8124876 | biostudies-literature
Unknown rac-2-Iodo-3,4-dihydro-naphthalen-1(2H)-one.
| S-EPMC2971913 | biostudies-literature
Unknown 7-Meth-oxy-3,4-dihydro-naphthalen-1(2H)-one.
| S-EPMC3152045 | biostudies-literature
Unknown 3,3'-Ethyl-enebis(3,4-dihydro-6-chloro-2H-1,3-benzoxazine).
| S-EPMC2979041 | biostudies-literature