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Ruthenium-catalyzed ?-carbolinium ion formation from aryl azides; synthesis of dimebolin.


ABSTRACT: A range of ?-carbolines were produced stereoselectively from ruthenium(III)-catalyzed reactions of 3-pyridyl substituted aryl azides. Other catalysts and conditions were neither as selective nor as high-yielding. This method was used to synthesize dimebolin in a concise and efficient manner.

SUBMITTER: Dong H 

PROVIDER: S-EPMC3097088 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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Ruthenium-catalyzed γ-carbolinium ion formation from aryl azides; synthesis of dimebolin.

Dong Huijun H   Latka Regina T RT   Driver Tom G TG  

Organic letters 20110425 10


A range of γ-carbolines were produced stereoselectively from ruthenium(III)-catalyzed reactions of 3-pyridyl substituted aryl azides. Other catalysts and conditions were neither as selective nor as high-yielding. This method was used to synthesize dimebolin in a concise and efficient manner. ...[more]

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