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Bis(?-2-{[2-(1,3-benzothia-zol-2-yl)hydrazinyl-idene]meth-yl}-6-meth-oxy-phenolato)bis-[dinitratodysprosium(III)] methanol disolvate.

ABSTRACT: In the centrosymmetric dinuclear title compound, [Dy(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(4)]·2CH(3)OH, the two Dy(III) atoms are coordinated by two deprotonated 2-{[2-(1,3-benzothia-zol-2-yl)hydrazinyl-idene]meth-yl}-6-meth-oxy-phenol ligands and four nitrate ions, all of which are chelating. The crystal packing is stabilized by inter-molecular N-H?O hydrogen bonds and weak O-H?O inter-actions, forming a two-dimensional network parallel to (010).

SUBMITTER: Xu X 

PROVIDER: S-EPMC3120308 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Bis(μ-2-{[2-(1,3-benzothia-zol-2-yl)hydrazinyl-idene]meth-yl}-6-meth-oxy-phenolato)bis-[dinitratodysprosium(III)] methanol disolvate.

Xu Xuebin X   Ding Shuai S   Shen Si S   Tang Jinkui J   Liu Zhiliang Z  

Acta crystallographica. Section E, Structure reports online 20110525 Pt 6

In the centrosymmetric dinuclear title compound, [Dy(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(4)]·2CH(3)OH, the two Dy(III) atoms are coordinated by two deprotonated 2-{[2-(1,3-benzothia-zol-2-yl)hydrazinyl-idene]meth-yl}-6-meth-oxy-phenol ligands and four nitrate ions, all of which are chelating. The crystal packing is stabilized by inter-molecular N-H⋯O hydrogen bonds and weak O-H⋯O inter-actions, forming a two-dimensional network parallel to (010). ...[more]

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