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{4,6-Bis[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene-?N)hydrazinyl-?N]pyrimidine-?N}dichloridocopper(II) methanol disolvate monohydrate.

ABSTRACT: The title compound, [CuCl(2)(C(18)H(18)N(8))]·2CH(3)OH·H(2)O, contains a penta-coordinated Cu(II) atom bonded to the tridentate 4,6-bis-[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene)hydrazin-yl]pyrimidine ligand and two Cl atoms. The geometry around the Cu(II) atom is distorted square-pyramidal. The mol-ecules pack in the crystal structure via O-H?Cl, O-H?N, C-H?Cl and C-H?O hydrogen bonds, C-H?? and ?-? inter-actions [centroid-centroid distances of the pyrimidine-pyridine and pyridine-pyridine inter-actions are 3.750?(3) and 3.850?(3)?Å, respectively], forming sheet-like assemblies.

SUBMITTER: Marzec B 

PROVIDER: S-EPMC3212151 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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{4,6-Bis[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene-κN)hydrazinyl-κN]pyrimidine-κN}dichloridocopper(II) methanol disolvate monohydrate.

Marzec Bartosz B   Mariyatra M Baby MB   McCabe Thomas T   Schmitt Wolfgang W  

Acta crystallographica. Section E, Structure reports online 20110709 Pt 8

The title compound, [CuCl(2)(C(18)H(18)N(8))]·2CH(3)OH·H(2)O, contains a penta-coordinated Cu(II) atom bonded to the tridentate 4,6-bis-[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene)hydrazin-yl]pyrimidine ligand and two Cl atoms. The geometry around the Cu(II) atom is distorted square-pyramidal. The mol-ecules pack in the crystal structure via O-H⋯Cl, O-H⋯N, C-H⋯Cl and C-H⋯O hydrogen bonds, C-H⋯π and π-π inter-actions [centroid-centroid distances of the pyrimidine-pyridine and pyridine-pyridine int  ...[more]

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