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Diaqua-bis-[5-(2-pyridyl-meth-yl)tetra-zol-ato-?N,N]zinc(II).


ABSTRACT: In the title mononuclear complex, [Zn(C(7)H(6)N(5))(2)(H(2)O)(2)], the Zn(II) atom, located on an inversion centre, is in a distorted octa-hedral coordination geometry formed by four N atoms from two chelating 5-(2-pyridyl-meth-yl)tetra-zolate ligands and two O donors from two water mol-ecules. Inter-molecular O-H?N hydrogen bonds between the coordinated water mol-ecule and the tetra-zolyl group of the 5-(2-pyridyl-meth-yl)tetra-zolate ligand lead to the formation of a three-dimensional network.

SUBMITTER: Liu Y 

PROVIDER: S-EPMC3120314 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Diaqua-bis-[5-(2-pyridyl-meth-yl)tetra-zol-ato-κN,N]zinc(II).

Liu Yang Y   Li Ya-Ling YL   Wang Xiu-Guang XG   Yang En-Cui EC  

Acta crystallographica. Section E, Structure reports online 20110528 Pt 6


In the title mononuclear complex, [Zn(C(7)H(6)N(5))(2)(H(2)O)(2)], the Zn(II) atom, located on an inversion centre, is in a distorted octa-hedral coordination geometry formed by four N atoms from two chelating 5-(2-pyridyl-meth-yl)tetra-zolate ligands and two O donors from two water mol-ecules. Inter-molecular O-H⋯N hydrogen bonds between the coordinated water mol-ecule and the tetra-zolyl group of the 5-(2-pyridyl-meth-yl)tetra-zolate ligand lead to the formation of a three-dimensional network. ...[more]

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