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Diaqua-bis{2-[5-(2-pyrid-yl)-2H-tetra-zol-2-yl]acetato-?N,N}zinc(II).

ABSTRACT: The title compound, [Zn(C(8)H(6)N(5)O(2))(2)(H(2)O)(2)], was synthesized by hydro-thermal reaction of ZnBr(2) with 2-[5-(2-pyrid-yl)-2H-tetra-zol-2-yl]acetic acid. The Zn(II) atom lies on an inversion center in a distorted octa-hedral environment with two planar trans-related N,N'-chelating 2-[5-(2-pyrid-yl)-2H-tetra-zol-2-yl]acetic acid ligands in the equatorial plane and two water mol-ecules in the axial positions. In the crystal, O-H?O hydrogen bonds generate an infinite three-dimensional network.

SUBMITTER: Wang B

PROVIDER: S-EPMC2969273 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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Diaqua-bis{2-[5-(2-pyrid-yl)-2H-tetra-zol-2-yl]acetato-κN,N}zinc(II).

Wang Bo B

Acta crystallographica. Section E, Structure reports online 20090627 Pt 7

The title compound, [Zn(C(8)H(6)N(5)O(2))(2)(H(2)O)(2)], was synthesized by hydro-thermal reaction of ZnBr(2) with 2-[5-(2-pyrid-yl)-2H-tetra-zol-2-yl]acetic acid. The Zn(II) atom lies on an inversion center in a distorted octa-hedral environment with two planar trans-related N,N'-chelating 2-[5-(2-pyrid-yl)-2H-tetra-zol-2-yl]acetic acid ligands in the equatorial plane and two water mol-ecules in the axial positions. In the crystal, O-H⋯O hydrogen bonds generate an infinite three-dimensional net ...[more]

PMID: 21582749

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