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Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers.

ABSTRACT: A series of ynenyl allyl ethers were rearranged into polysubstituted furans in the presence of a gold(I) catalyst. It is proposed that the transformation involves a Claisen-type rearrangement that allows the efficient creation of quaternary centers under mild experimental conditions.

SUBMITTER: Istrate FM 

PROVIDER: S-EPMC3135071 | biostudies-literature | 2011

REPOSITORIES: biostudies-literature

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Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers.

Istrate Florin M FM   Gagosz Fabien F  

Beilstein journal of organic chemistry 20110629

A series of ynenyl allyl ethers were rearranged into polysubstituted furans in the presence of a gold(I) catalyst. It is proposed that the transformation involves a Claisen-type rearrangement that allows the efficient creation of quaternary centers under mild experimental conditions. ...[more]

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