Ontology highlight
ABSTRACT:
SUBMITTER: Chuprakov S
PROVIDER: S-EPMC3142877 | biostudies-literature | 2011 Jul
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20110620 27
A highly efficient enantioselective C-H insertion of azavinyl carbenes into unactivated alkanes has been developed. These transition metal carbenes are directly generated from readily available and stable 1-sulfonyl-1,2,3-triazoles in the presence of chiral Rh(II) carboxylates and are used for C-H functionalization of alkanes to access a variety of β-chiral sulfonamides. ...[more]