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N-(2-Hy-droxy-benz-yl)adamantan-1-aminium chloride.

ABSTRACT: The asymmetric unit of the title compound, C(17)H(24)NO(+)·Cl(-), consists of a discrete N-(2-hy-droxy-benz-yl)adamantan-1-aminium cation and a Cl(-) anion. Inter-molecular N-H?Cl and O-H?Cl hydrogen bonds occurring between the organic cation and the Cl(-) anion generate a layered structure.

SUBMITTER: Rong T

PROVIDER: S-EPMC3151742 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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N-(2-Hy-droxy-benz-yl)adamantan-1-aminium chloride.

Rong Tao T

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7

The asymmetric unit of the title compound, C(17)H(24)NO(+)·Cl(-), consists of a discrete N-(2-hy-droxy-benz-yl)adamantan-1-aminium cation and a Cl(-) anion. Inter-molecular N-H⋯Cl and O-H⋯Cl hydrogen bonds occurring between the organic cation and the Cl(-) anion generate a layered structure. ...[more]

PMID: 21837010

Similar Datasets

N-(2-Hy-droxy-benz-yl)adamantan-1-aminium bromide.

Project description:There are two independent ion pairs in the asymmetric unit of the title compound, C(17)H(24)NO(+)·Br(-). In the crystal, the ions are linked by inter-molecular N-H?Br and O-H?Br hydrogen bonds.

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N-(2-Hy-droxy-benz-yl)adamantan-1-aminium 4-methyl-benzene-sulfonate.

Project description:In the crystal structure of the title salt, C(17)H(24)NO(+)·C(7)H(7)O(3)S(-), the N-(2-hy-droxy-benz-yl)adamantan-1-aminium cations and 4-methyl-benzene-sulfonate anions are linked by O-H?O and N-H?O hydrogen bonds. C-H?? inter-actions are also observed between the cation and the anion.

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Project description:The non-symmetric title mol-ecule, C32H34N2O5, is based on a tetra-substituted ethyl-enedi-amine backbone. The mol-ecular structure consists of three hy-droxy-benzyl groups and one 2-hy-droxy-5-methyl-benzaldehyde group bonded to the N atoms of the di-amine unit. The ethyl-enedi-amine skeleton shows a regular extended conformation, while the spatial orientation of the phenol arms is governed by hydrogen bonds. In the 2-hy-droxy-5-methyl-benzaldehyde group, an intra-molecular S(6) O-H?O hydrogen bond is observed between the alcohol and aldehyde functions, and the neighbouring phenol arm participates in an intra-molecular S(6) O-H?N hydrogen bond. The third phenol group is involved in a bifurcated intra-molecular hydrogen bond with graph-set notation S(6) for O-H?N and O-H?O intra-molecular hydrogen bonds between neighbouring amine and phenol arms, respectively. Finally, the fourth phenol group acts as an acceptor in a bifurcated intra-molecular hydrogen bond and also acts as donor in an inter-molecular hydrogen bond, which connects inversion-related mol-ecules into dimers with R 4 (4)(8) ring motifs.

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(tert-But-yl)(2-hy-droxy-eth-yl)ammonium chloride.

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rac-3-(4-Hy-droxy-benz-yl)chroman-4-one.

Project description:In the racemic title compound, C16H14O3, the ring of the 4-hy-droxy-benzyl substituent group forms a dihedral angle of 80.12?(12)° with the benzene ring of the chromanone system. Two C atoms of the pyran-one ring and the H atoms on the benzyl ?-C atom are disordered over two sites, with site-occupation factors of 0.818?(8) and 0.182?(8). The crystal structure is stabilized by O-H?O hydrogen bonds, which form parallel one-dimensional zigzag chains down the c axis and are inter-connected by both methine C-H?O hydrogen bonds and weak aromatic C-H?? inter-actions, giving a sheet structure lying parallel to [011].

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