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N-(2-Hy-droxy-benz-yl)adamantan-1-aminium 4-methyl-benzene-sulfonate.

ABSTRACT: In the crystal structure of the title salt, C(17)H(24)NO(+)·C(7)H(7)O(3)S(-), the N-(2-hy-droxy-benz-yl)adamantan-1-aminium cations and 4-methyl-benzene-sulfonate anions are linked by O-H?O and N-H?O hydrogen bonds. C-H?? inter-actions are also observed between the cation and the anion.

SUBMITTER: Hou SG

PROVIDER: S-EPMC3239026 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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N-(2-Hy-droxy-benz-yl)adamantan-1-aminium 4-methyl-benzene-sulfonate.

Hou Shao-Gang SG

Acta crystallographica. Section E, Structure reports online 20111119 Pt 12

In the crystal structure of the title salt, C(17)H(24)NO(+)·C(7)H(7)O(3)S(-), the N-(2-hy-droxy-benz-yl)adamantan-1-aminium cations and 4-methyl-benzene-sulfonate anions are linked by O-H⋯O and N-H⋯O hydrogen bonds. C-H⋯π inter-actions are also observed between the cation and the anion. ...[more]

PMID: 22199874

Similar Datasets

N-(2-Hy-droxy-benz-yl)adamantan-1-aminium bromide.

Project description:There are two independent ion pairs in the asymmetric unit of the title compound, C(17)H(24)NO(+)·Br(-). In the crystal, the ions are linked by inter-molecular N-H?Br and O-H?Br hydrogen bonds.

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N-(2-Hy-droxy-benz-yl)adamantan-1-aminium chloride.

Project description:The asymmetric unit of the title compound, C(17)H(24)NO(+)·Cl(-), consists of a discrete N-(2-hy-droxy-benz-yl)adamantan-1-aminium cation and a Cl(-) anion. Inter-molecular N-H?Cl and O-H?Cl hydrogen bonds occurring between the organic cation and the Cl(-) anion generate a layered structure.

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Bis[N-(2-hy-droxy-benz-yl)adamantan-1-aminium] fluoride tetra-fluoro-borate monohydrate.

Project description:In the title compound, 2C(17)H(24)NO(+)·BF(4) (-)·F(-)·H(2)O, the asymmetric unit contains two N-(2-hy-droxy-benz-yl)adamantan-1-aminium cations, one BF(4) (-) anion, one F(-) anion and one water mol-ecule. Both amine N atoms are protonated. The hy-droxy O atoms, amino N atoms and water O atom are involved in inter-molecular O-H?O, O-H?F, N-H?O and N-H?F hydrogen bonding.

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4-(4-Nitro-benz-yl)pyridinium 3-carb-oxy-4-hy-droxy-benzene-sulfonate.

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Project description:In the crystal of the title molecular salt, C7H10N(+)·C6H5O4S(-), the benzene-sulfonate units are linked through phenol-sulfonate O-H?O hydrogen bonds, forming chains along the c-axis direction. These chains are linked via N-H?O hydrogen bonds involving two of the three H atoms of the ammonium group of the 4-methyl-anilium cation, giving rise to two-dimensional networks parallel to the bc plane which are further connected through an additional N-H?O inter-action in which the third ammonium H atom is involved, generating a three-dimensional network.

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Project description:In the crystal structure of the title salt, C(2)H(8)NO(+)·C(7)H(6)NO(5)S(-), the cations and anions are linked together by N-H⋯O and O-H⋯O hydrogen bonds, forming layers parallel to (100). The plane of nitro group is skew with respect to the plane of benzene ring, making a dihedral angle of 17.5 (2)°.

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Project description:In the title mol-ecule, C(37)H(48)O(4)S, the benzene rings in the biphenyl fragment are inclined to each other at 61.1?(1)°. The hy-droxy group is involved in a weak intra-molecular O-H?O(sulfonate) hydrogen bond. One tert-butyl group is disodered over two orientations in a 0.682?(17):0.318?(17) ratio. In the crystal, weak C-H?O hydrogen bonds link the mol-ecules into columns in direction [100].

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(3,4-Dihy-droxy-oxolan-2-yl)methyl 4-methyl-benzene-sulfonate.

Project description:The racemic title compound, C(12)H(16)O(6)S, possesses a five-membered ring that adopts an envelope-shaped conformation; the two hy-droxy groups occupy quasi-axial positions. Adjacent mol-ecules are linked by O-H?O hydrogen bonds to generate a ribbon that runs along the a axis of the ortho-rhom-bic unit cell. The crystal studied was an inversion twin.

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Adamantan-1-aminium p-toluene-sulfonate.

Project description:There are two unique cations and anions in the asymmetric unit of the title mol-ecular salt, C(10)H(15)NH(3) (+)·C(7)H(7)O(3)S(-). In the crystal, all three hydrogen-bond donors of the protonated amine group make hydrogen-bond inter-actions with sulfonate O-atom acceptors, linking the cations and anions into chains parallel to the a axis. C-H⋯π inter-actions are also present.

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2-Amino-5-methyl-pyridinium 3-carb-oxy-4-hy-droxy-benzene-sulfonate.

Project description:The asymmetric unit of the title salt, C(6)H(9)N(2) (+)·C(7)H(5)O(6)S(-), contains two crystallographically independent 2-amino-5-methylpyridinium cations and two sulfosalicylate anions. In the crystal structure, the sulfonate group of each 3-carb-oxy-4-hy-droxy-benzene-sulfonate anion inter-acts with the corresponding 2-amino-5-methyl-pyridinium cation via a pair of N-H?O hydrogen bonds, forming an R(2) (2)(8) ring motif. The ionic units are linked by N-H?O, O-H?O and C-H?O hydrogen bonds. Furthermore, the crystal structure is stabilized by ?-? inter-actions between the benzene and pyridine rings [centroid-centroid distances = 3.5579?(8) and 3.8309?(8)?Å]. There are also intra-molecular O-H?O hydrogen bonds in the anions, which generate S(6) ring motifs.

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