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N-(2-Hy-droxy-benz-yl)adamantan-1-aminium 4-methyl-benzene-sulfonate.

ABSTRACT: In the crystal structure of the title salt, C(17)H(24)NO(+)·C(7)H(7)O(3)S(-), the N-(2-hy-droxy-benz-yl)adamantan-1-aminium cations and 4-methyl-benzene-sulfonate anions are linked by O-H?O and N-H?O hydrogen bonds. C-H?? inter-actions are also observed between the cation and the anion.

SUBMITTER: Hou SG

PROVIDER: S-EPMC3239026 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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N-(2-Hy-droxy-benz-yl)adamantan-1-aminium 4-methyl-benzene-sulfonate.

Hou Shao-Gang SG

Acta crystallographica. Section E, Structure reports online 20111119 Pt 12

In the crystal structure of the title salt, C(17)H(24)NO(+)·C(7)H(7)O(3)S(-), the N-(2-hy-droxy-benz-yl)adamantan-1-aminium cations and 4-methyl-benzene-sulfonate anions are linked by O-H⋯O and N-H⋯O hydrogen bonds. C-H⋯π inter-actions are also observed between the cation and the anion. ...[more]

PMID: 22199874

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N-(2-Hy-droxy-benz-yl)adamantan-1-aminium bromide.

Project description:There are two independent ion pairs in the asymmetric unit of the title compound, C(17)H(24)NO(+)·Br(-). In the crystal, the ions are linked by inter-molecular N-H?Br and O-H?Br hydrogen bonds.

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N-(2-Hy-droxy-benz-yl)adamantan-1-aminium chloride.

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Project description:The racemic title compound, C(12)H(16)O(6)S, possesses a five-membered ring that adopts an envelope-shaped conformation; the two hy-droxy groups occupy quasi-axial positions. Adjacent mol-ecules are linked by O-H?O hydrogen bonds to generate a ribbon that runs along the a axis of the ortho-rhom-bic unit cell. The crystal studied was an inversion twin.

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Project description:There are two unique cations and anions in the asymmetric unit of the title mol-ecular salt, C(10)H(15)NH(3) (+)·C(7)H(7)O(3)S(-). In the crystal, all three hydrogen-bond donors of the protonated amine group make hydrogen-bond inter-actions with sulfonate O-atom acceptors, linking the cations and anions into chains parallel to the a axis. C-H⋯π inter-actions are also present.

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2-Amino-5-methyl-pyridinium 3-carb-oxy-4-hy-droxy-benzene-sulfonate.

Project description:The asymmetric unit of the title salt, C(6)H(9)N(2) (+)·C(7)H(5)O(6)S(-), contains two crystallographically independent 2-amino-5-methylpyridinium cations and two sulfosalicylate anions. In the crystal structure, the sulfonate group of each 3-carb-oxy-4-hy-droxy-benzene-sulfonate anion inter-acts with the corresponding 2-amino-5-methyl-pyridinium cation via a pair of N-H⋯O hydrogen bonds, forming an R(2) (2)(8) ring motif. The ionic units are linked by N-H⋯O, O-H⋯O and C-H⋯O hydrogen bonds. Furthermore, the crystal structure is stabilized by π-π inter-actions between the benzene and pyridine rings [centroid-centroid distances = 3.5579 (8) and 3.8309 (8) Å]. There are also intra-molecular O-H⋯O hydrogen bonds in the anions, which generate S(6) ring motifs.

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