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N-(3-Chloro-4-fluoro-phen-yl)-2-(naphthalen-1-yl)acetamide.

ABSTRACT: In the title compound, C(18)H(13)ClFNO, the dihedral angle between the mean planes of the chloro- and fluoro-substituted benzene ring and the naphthalene ring system is 60.5 (8)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming a zigzag chain along [101].

SUBMITTER: Praveen AS

PROVIDER: S-EPMC3151961 | biostudies-literature |

REPOSITORIES: biostudies-literature

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N-(4-Chloro-phen-yl)-2-(naphthalen-1-yl)acetamide.

Project description:In the title compound, C(18)H(14)ClNO, the naphthalene ring system [maximum deviation = 0.014 (9) Å] forms a dihedral angle of 74.8 (2)° with the benzene ring. In the crystal, mol-ecules are linked via N-H⋯O hydrogen bonds into chains propagating along [010].

| S-EPMC3414919 | biostudies-literature

2-Chloro-N-(4-fluoro-phen-yl)acetamide.

Project description:In the title compound, C(8)H(7)ClFNO, an intra-molecular C-H?O hydrogen bond forms a six-membered ring. In the crystal structure, mol-ecules are linked by inter-molecular N-H?O hydrogen bonds, forming infinite chains along the c axis.

| S-EPMC2961718 | biostudies-literature

N-(3-Chloro-4-fluoro-phen-yl)acetamide.

Project description:In the title compound, C(8)H(7)ClFNO, the dihedral angle between the benzene ring and the acetamide side chain is 5.47 (6)°. An S(6) ring motif is formed via an intra-molecular C-H⋯O hydrogen bond. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into C(4) chains along [001].

| S-EPMC3344482 | biostudies-literature

2-(4-Chloro-phen-yl)-N-(3,4-di-fluoro-phen-yl)acetamide.

Project description:In the title compound, C14H10ClF2NO, the dihedral angle between the mean planes of the 4-chloro-phenyl and 3,4-di-fluoro-phenyl rings is 65.2 (1)°. These two planes are twisted by 83.5 (5) and 38.9 (9)°, respectively, from that of the acetamide group. In the crystal, N-H⋯O hydrogen bonds form infinite chains along [100]. Weak C-H⋯O and C-H⋯F inter-actions are also observed and stack mol-ecules along the b axis.

| S-EPMC3685127 | biostudies-literature

2-(4-Bromo-phen-yl)-N-(3-chloro-4-fluoro-phen-yl)acetamide.

Project description:In the title compound, C(14)H(10)BrClFNO, the benzene rings form a dihedral angle of 64.0?(2)°. In the crystal, mol-ecules are linked via inter-molecular N-H?O, C-H?O, C-H?Cl and C-H?F hydrogen bonds into layers parallel to (001). The crystal was refined as a merohedral twin with a 0.935?(114):0.065?(14) domain ratio.

| S-EPMC3415000 | biostudies-literature

Crystal structure of 2-chloro-N-(3-fluoro-phen-yl)acetamide.

Project description:In the title compound, C8H7ClFNO, the F atom is disordred over the meta positions of the benzene ring in a 0.574?(4):0.426?(4) ratio and the Cl atom is syn to the O atom [O-C-C-Cl = 5.6?(3)°]. A short intra-molecular C-H?O contact occurs. In the crystal, mol-ecules are linked into amide C(4) chains propagating in [101] by N-H?O hydrogen bonds.

| S-EPMC4420121 | biostudies-literature

2-Chloro-N-[2-(2-fluoro-benzo-yl)-4-nitro-phen-yl]-N-methyl-acetamide.

Project description:The title compound, C(16)H(12)ClFN(2)O(4), crystallizes with two mol-ecules in the asymmetric unit in which the dihedral angles between the mean planes of the two benzene rings are 65.1 (7) and 65.6 (6)°. In each mol-ecule, the nitro group displays rotational disorder over two orientations in a 0.503 (11):0.497 (11) ratio and the Cl atom is disordered in a 0.432 (5):0.568 (5) ratio. In one mol-ecule, the F atoms is statistically disordered over two positions. The crystal packing features weak inter-molecular C-H⋯O and C-H⋯Cl inter-actions, which form a layered network.

| S-EPMC3200782 | biostudies-literature

N-(2-Bromo-phen-yl)-2-(naphthalen-1-yl)acetamide.

Project description:In the title compound, C(18)H(14)BrNO, the naphthalene ring system [maximum deviation = 0.015 (3) Å] forms a dihedral angle of 67.70 (10)° with the benzene ring. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds into C(4) chains propagating in [100]. A C-H⋯O inter-action reinforces the chain connectivity, generating an R(2) (1)(6) loop.

| S-EPMC3435683 | biostudies-literature

N-(2,6-Dichloro-phen-yl)-2-(naphthalen-1-yl)acetamide.

Project description:In the title compound, C(18)H(13)Cl(2)NO, the naphthalene ring system and the benzene ring form dihedral angles of 74.73 (13) and 62.53 (16)°, respectively, with the acetamide grouping [maximum deviation = 0.005 (3) Å]. The naphthalene ring system forms a dihedral angle of 75.14 (13)° with the benzene ring. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, forming C(4) chains propagating in [010]. The O atom also accepts two C-H⋯O inter-actions.

| S-EPMC3344513 | biostudies-literature

N-(3-Chloro-phen-yl)acetamide.

Project description:The conformation of the N-H bond in the structure of the title compound (3CPA), C(8)H(8)ClNO, is anti to the meta-chloro substituent, in contrast to the syn conformation observed for the ortho-chloro substituent in N-(2-chloro-phen-yl)acetamide, syn to both the ortho and meta chloro substituents in N-(2,3-dichloro-phen-yl)acetamide, and syn to the ortho chloro substituent in N-(2,4-dichloro-phen-yl)acetamide. There are two mol-ecules, linked by an N-H⋯O hydrogen bond, in the asymmetric unit of 3CPA. The bond parameters in 3CPA are similar to those of other acetanilides and the mol-ecules are packed into chains through inter-molecular N-H⋯O hydrogen bonds.

| S-EPMC2960357 | biostudies-literature

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