Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

4-[(E)-(4-Fluoro-benzyl-idene)amino]-phenol.

ABSTRACT: In the title compound, C(13)H(10)FNO, the dihedral angle between the aromatic rings is 55.60?(8)°. In the crystal, mol-ecules are linked by O-H-N hydrogen bonds, forming zigzag C(7) chains propagating in [101].

SUBMITTER: Sun LX

PROVIDER: S-EPMC3152012 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

4-[(E)-(4-Fluoro-benzyl-idene)amino]-phenol.

Sun Li-Xia LX Yu Yun-Dan YD Wei Guo-Ying GY

Acta crystallographica. Section E, Structure reports online 20110604 Pt 7

In the title compound, C(13)H(10)FNO, the dihedral angle between the aromatic rings is 55.60 (8)°. In the crystal, mol-ecules are linked by O-H-N hydrogen bonds, forming zigzag C(7) chains propagating in [101]. ...[more]

PMID: 21836989

Similar Datasets

2-[(2-Meth-oxy-benzyl-idene)amino]-phenol.

Project description:In the title compound, C(14)H(13)NO(2), the azomethine double bond adopts an E conformation and the benzene rings form a dihedral angle of 77.70?(7)°. In the crystal, mol-ecules are linked by O-H?N and C-H?O hydrogen bonds and arranged in a zigzag fashion, forming infinite chains parallel to the c axis, resulting in a graph-set R(2) (2)(9) motif.

| S-EPMC3344564 | biostudies-literature

(E)-4-[(4-Bromo-benzyl-idene)amino]phenol.

Project description:In the title compound, C(13)H(10)BrNO, the dihedral angle between the benzene rings is 35.20?(8)°. In the crystal, mol-ecules are linked by O-H?N hydrogen bonds, forming a zigzag chain along the a axis. A weak C-H?? inter-action is observed between the chains.

| S-EPMC2979767 | biostudies-literature

4-[(E)-(4-Eth-oxy-benzyl-idene)amino]-phenol.

Project description:The mol-ecule of the title compound, C15H15NO2, adopts a trans conformation with respect to the methyl-idene C=N bond and is twisted with a dihedral angle of 26.31?(5)° between the two substituted benzene rings. The eth-oxy group is almost coplanar with the bound benzene ring with a C-O-C-C torsion angle of -179.08?(9)°. In the crystal, mol-ecules are linked by O-H?N hydrogen bonds and weak C-H?O inter-actions into chains propagating in the [011] and [01-1] directions. C-H?? inter-actions are also present.

| S-EPMC3685059 | biostudies-literature

4-[(E)-(4-Fluoro-benzyl-idene)amino]-benzoic acid.

Project description:In the title compound, C(14)H(10)FNO(2), the benzene rings make a dihedral angle of 57.50?(13)°, and the molecule has an E configuration about the C=N bond. In the crystal, molecules are linked via pairs of O-H?O hydrogen bonds, forming inversion dimers.

| S-EPMC3254514 | biostudies-literature

Crystal structure of [2-({2-[(2-azanidyl-benzyl-idene)amino]-benzyl-idene}amino)-4-chloro-phenol-ato]nickel(II).

Project description:The title complex, [Ni(C20H14ClN3O)], with an asymmetrically chloride-appended Schiff base ligand has been synthesized and structurally characterized at 100 K. In the compound, the central nickel(II) ion has a square-planar coordination geometry with N3O donors of the π-conjugated tetra-dentate Schiff base ligand. In the crystal, the complexes are connected into an inversion dimer via an Ni⋯Ni inter-action [3.1753 (5) Å] and a pair of π-π inter-actions [centroid-centroid distance = 3.8416 (16) Å]. The dimers are linked via a C-H⋯Cl hydrogen bond, forming a chain along the c-axis direction. The dimer chains inter-act with each other through π-π inter-actions [centroid-centroid distance = 3.8736 (16) Å], forming a layer expanding parallel to the ac plane.

| S-EPMC5382639 | biostudies-literature

(E)-2-{[4-(Di-methyl-amino)-benzyl-idene]amino}-5-nitro-phenol.

Project description:The title Schiff base compound, C15H15N3O3, crystallizes with two mol-ecules (A and B) in the asymmetric unit. Each mol-ecule adopts an E conformation around the C= N imine bond. The two mol-ecules have minor differences in their conformations. In mol-ecule A, the dihedral angle between the nitro group and its benzene ring is 2.1?(2)° and that between the two benzene rings is 0.88?(7)°, while the corresponding angles for mol-ecule B are 5.7?(1) and 2.45?(6)°, respectively. In each mol-ecule, there is an intra-molecular O-H?N hydrogen bond. In the crystal, inversion-related mol-ecules are linked via O-H?O hydrogen bonds forming A-A and B-B dimers. These dimers are linked via C-H?O hydrogen bonds involving the nitro O atoms, forming A-A-A and B-B-B slabs that lie parallel to one another and to (010).

| S-EPMC4011306 | biostudies-literature

(E)-4-Chloro-2-{[4-(di-methyl-amino)-benzyl-idene]amino}-phenol.

Project description:In the title aromatic Schiff base compound, C15H15ClN2O, the mol-ecule exists in a trans conformation with respect to the C=N bond. The dihedral angle between the benzene rings is 14.49 (6)°. In the crystal, weak C-H⋯π inter-actions link mol-ecules into supra-molecular chains propagated along the a-axis direction.

| S-EPMC4011262 | biostudies-literature

(E)-2-[(2,4,6-Tri-meth-oxy-benzyl-idene)amino]-phenol.

Project description:There are two independent mol-ecules in the asymmetric unit of the title compound, C16H17NO4, with similar conformations but some differences in their bond angles. Each mol-ecule adopts a trans configuration with respect to the methyl-idene C=N bond and is twisted with a dihedral angle between the two substituted benzene rings of 80.52 (7)° in one mol-ecule and 83.53 (7)° in the other. All meth-oxy groups are approximately coplanar with the attached benzene rings, with Cmeth-yl-O-C-C torsion angles ranging from -6.7 (2) to 5.07 (19)°. In the crystal, independent mol-ecules are linked together by O-H⋯N and O-H⋯O hydrogen bonds and a π-π inter-action [centroid-centroid distance of 3.6030 (9) Å], forming a dimer. The dimers are further linked by weak C-H⋯O inter-actions and another π-π inter-action [centroid-centroid distance of 3.9452 (9) Å] into layers lying parallel to the ab plane.

| S-EPMC3914096 | biostudies-literature

4-(2,3,4-Trimeth-oxy-6-methyl-benzyl-idene-amino)phenol.

Project description:The asymmetric unit of the title compound, C(17)H(19)NO(4), contains two independent mol-ecules in which the dihedral angles between the two benzene rings are 83.1 (2) and 88.5 (2)°. Each mol-ecule adopts a trans configuration with respect to the C=N bond. In the crystal structure, mol-ecules are linked by inter-molecular O-H⋯N hydrogen bonds, forming two independent one-dimensional chains running along the b-axis direction.

| S-EPMC2969002 | biostudies-literature

2-[(3,4-Di-chloro-benzyl-idene)amino]-4-methyl-phenol.

Project description:In the title compound, C14H11Cl2NO, the dihedral angle between the benzene rings is 15.36 (8)°. A phenol-imine-type intra-molecular O-H⋯N hydrogen bond generates an S(5) ring motif. In the crystal, a pair of weak C-H⋯O hydrogen bonds form an R 2 (1)(7) ring motif involving glide-plane-related mol-ecules. The mol-ecules linked via these inter-actions form chains along [101].

| S-EPMC3685100 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data