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3-(2-Bromo-benz-yl)-1-methyl-1H-imidazol-3-ium bromide.

ABSTRACT: In the title compound, C(11)H(12)BrN(2) (+)·Br(-), the imidazole and phenyl rings are nearly perpendicular, making a dihedral angle of 87.71?(7)°. The crystal structure is stabilized by non-classical inter-molecular C-H?Br hydrogen bonds and inversion-related mol-ecules are linked through ?-? inter-actions between the imidazole ring systems [centroid-centroid distance = 3.472?(6)?Å].

SUBMITTER: Dong JY

PROVIDER: S-EPMC3152033 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

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3-(2-Bromo-benz-yl)-1-methyl-1H-imidazol-3-ium bromide.

Dong Jian-Yu JY You Tian-Pa TP

Acta crystallographica. Section E, Structure reports online 20110604 Pt 7

In the title compound, C(11)H(12)BrN(2) (+)·Br(-), the imidazole and phenyl rings are nearly perpendicular, making a dihedral angle of 87.71 (7)°. The crystal structure is stabilized by non-classical inter-molecular C-H⋯Br hydrogen bonds and inversion-related mol-ecules are linked through π-π inter-actions between the imidazole ring systems [centroid-centroid distance = 3.472 (6) Å]. ...[more]

PMID: 21836980

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