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[4-(Bromo-methyl)-benz-yl]triphenyl-phospho-nium bromide acetonitrile monosolvate.

ABSTRACT: In the title compound, C(26)H(23)BrP(+)·Br(-)·C(2)H(3)N, the dihedral angles between the plane of the benzylic phenyl ring attached to the P atom and the planes of the three directly attached phenyl rings are 34.04?(12), 45.48?(13) and 87.18?(9)°. In the crystal, centrosymmetric pairs of cations and anions are linked into dimeric aggregates via C-H?Br hydrogen bonds. There is also a C-H?N hydrogen bond to the acetonitrile solvent mol-ecule.

SUBMITTER: Burke BP 

PROVIDER: S-EPMC3515291 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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[4-(Bromo-methyl)-benz-yl]triphenyl-phospho-nium bromide acetonitrile monosolvate.

Burke Benjamin P BP   Greenman Peter P   Smith Adam M AM   Archibald Stephen J SJ  

Acta crystallographica. Section E, Structure reports online 20121024 Pt 11

In the title compound, C(26)H(23)BrP(+)·Br(-)·C(2)H(3)N, the dihedral angles between the plane of the benzylic phenyl ring attached to the P atom and the planes of the three directly attached phenyl rings are 34.04 (12), 45.48 (13) and 87.18 (9)°. In the crystal, centrosymmetric pairs of cations and anions are linked into dimeric aggregates via C-H⋯Br hydrogen bonds. There is also a C-H⋯N hydrogen bond to the acetonitrile solvent mol-ecule. ...[more]

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