Ontology highlight
ABSTRACT:
SUBMITTER: Conley BL
PROVIDER: S-EPMC3168700 | biostudies-literature | 2011 Sep
REPOSITORIES: biostudies-literature
Conley Brian L BL Guess Denver D Williams Travis J TJ
Journal of the American Chemical Society 20110818 36
We describe an efficient homogeneous ruthenium catalyst for the dehydrogenation of ammonia borane (AB). This catalyst liberates more than 2 equiv of H(2) and up to 4.6 system wt % H(2) from concentrated AB suspensions under air. Importantly, this catalyst is robust, delivering several cycles of dehydrogenation at high [AB] without loss of catalytic activity, even with exposure to air and water. ...[more]