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Catena-Poly[[bis-[[bis-(3-amino-prop-yl)amine-?N,N',N''](thio-cyanato-?N)cadmium]-?(4)-sulfato-?O,O:O',O'] methanol hemisolvate].

ABSTRACT: The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thio-cyanate and one sulfate anion, two bis-(3-amino-prop-yl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by four N atoms of one terminal N-bonded thio-cyanate anion and one bis-(3-amino-prop-yl)amine co-ligand, and by two O atoms of two symmetry-related sulfate anions, defining a slightly distorted octa-hedral coordination polyhedron. Each two Cd(2+) cations are connected into dimers, which are located on centres of inversion and which are further ?-1,1:3,3-bridged via the sulfate anions into polymeric zigzag chains along the a axis.

SUBMITTER: Boeckmann J

PROVIDER: S-EPMC3200697 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-[[bis-(3-amino-prop-yl)amine-κN,N',N''](thio-cyanato-κN)cadmium]-μ(4)-sulfato-κO,O:O',O'] methanol hemisolvate].

Boeckmann Jan J Näther Christian C

Acta crystallographica. Section E, Structure reports online 20110806 Pt 9

The asymmetric unit of the title compound, {[Cd(2)(NCS)(2)(SO(4))(C(6)H(17)N(3))(2)]·0.5CH(3)OH}(n), consists of two Cd(2+) cations, two thio-cyanate and one sulfate anion, two bis-(3-amino-prop-yl)amine co-ligands and one methanol molecule with half-occupancy. Each Cd(2+) cation is coordinated by four N atoms of one terminal N-bonded thio-cyanate anion and one bis-(3-amino-prop-yl)amine co-ligand, and by two O atoms of two symmetry-related sulfate anions, defining a slightly distorted octa-hedr ...[more]

PMID: 22058845

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catena-Poly[[dimethyl-bis-(thio-cyanato-κN)tin(IV)]-μ-(4,4'-bipyridine-κN:N')].

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catena-Poly[[bis-(pyridine-κN)cadmium]-di-μ(2)-thio-cyanato-κN:S;κS:N].

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