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Bis(thio-cyanato-?N)[tris-(2-pyridylmeth-yl)amine-?N,N',N'',N''']nickel(II) methanol hemisolvate.

ABSTRACT: The title complex, [Ni(NCS)(2)(C(18)H(18)N(4))]·0.5CH(3)OH, consists of two crystallographically distinct complexes and a methanol solvent mol-ecule. The Ni(II) complexes are pseudo-octa-hedral six-coordinate, with the tris-(2-pyridylmeth-yl)amine (TPA) ligand providing four N atoms and two N-bound thio-cyanates providing the final two N atoms. The distances and angles are typical for Ni(II)-TPA complexes. The compound has unit-cell parameters that are surprisingly similar to the previously reported hydrate.

SUBMITTER: Randeniya SR 

PROVIDER: S-EPMC2969451 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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Bis(thio-cyanato-κN)[tris-(2-pyridylmeth-yl)amine-κN,N',N'',N''']nickel(II) methanol hemisolvate.

Randeniya Sajini R SR   Norman Richard E RE  

Acta crystallographica. Section E, Structure reports online 20090613 Pt 7

The title complex, [Ni(NCS)(2)(C(18)H(18)N(4))]·0.5CH(3)OH, consists of two crystallographically distinct complexes and a methanol solvent mol-ecule. The Ni(II) complexes are pseudo-octa-hedral six-coordinate, with the tris-(2-pyridylmeth-yl)amine (TPA) ligand providing four N atoms and two N-bound thio-cyanates providing the final two N atoms. The distances and angles are typical for Ni(II)-TPA complexes. The compound has unit-cell parameters that are surprisingly similar to the previously repo  ...[more]

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