Unknown

Dataset Information

0

Rac-2-{[1-(1-Adamant-yl)eth-yl]imino-meth-yl}-5-meth-oxy-phenol.

ABSTRACT: A novel Schiff base compound, C(20)H(27)NO(2), was obtained by a condensation of rimantadine and 2-hy-droxy-4-meth-oxy-benzaldehyde. An intra-molecular O-H?N hydrogen bond supports the phenol-imine tautomeric form. The adamantane and imino-methyl-4-meth-oxy-phenol units are arranged in a folded conformation [C-N-C-C torsion angle = 110.9?(3)°]. In the crystal, highly hydro-phobic adamantane moieties are inserted between the imino-methyl-4-meth-oxy-phenol units in a sandwich-like arrangement along the c axis.

SUBMITTER: Jin XD 

PROVIDER: S-EPMC3200738 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

rac-2-{[1-(1-Adamant-yl)eth-yl]imino-meth-yl}-5-meth-oxy-phenol.

Jin Xu-Dong XD   Wang Hai-Bo HB   Jin Yue-Hong YH  

Acta crystallographica. Section E, Structure reports online 20110802 Pt 9

A novel Schiff base compound, C(20)H(27)NO(2), was obtained by a condensation of rimantadine and 2-hy-droxy-4-meth-oxy-benzaldehyde. An intra-molecular O-H⋯N hydrogen bond supports the phenol-imine tautomeric form. The adamantane and imino-methyl-4-meth-oxy-phenol units are arranged in a folded conformation [C-N-C-C torsion angle = 110.9 (3)°]. In the crystal, highly hydro-phobic adamantane moieties are inserted between the imino-methyl-4-meth-oxy-phenol units in a sandwich-like arrangement alon  ...[more]

Similar Datasets

Unknown 2-Eth-oxy-6-[(methyl-imino)-meth-yl]phenol.
| S-EPMC3006704 | biostudies-literature
Unknown 4-[(E)-(4-Eth-oxy-phen-yl)imino-meth-yl]phenol.
| S-EPMC3435674 | biostudies-literature
Unknown 2-Eth-oxy-6-[(3-methyl-pyridin-2-yl)-imino-meth-yl]phenol.
| S-EPMC3089178 | biostudies-literature
Unknown (E)-2-Eth-oxy-6-[(4-ethoxy-phen-yl)imino-meth-yl]phenol.
| S-EPMC2983578 | biostudies-literature
Unknown 2-Eth-oxy-6-{(E)-[(4-methyl-phen-yl)imino]-meth-yl}phenol.
| S-EPMC3393282 | biostudies-literature
Unknown 2-[({2-[(2-Hy-droxy-5-meth-oxy-benzyl-idene)amino]-eth-yl}imino)-meth-yl]-4-meth-oxy-phenol.
| S-EPMC3379345 | biostudies-literature
Unknown 5-Diethyl-amino-2-[(E)-(4-eth-oxy-phen-yl)imino-meth-yl]phenol.
| S-EPMC3051950 | biostudies-literature
Unknown 2-Eth-oxy-6-({2-[(3-eth-oxy-2-hy-droxy-benzyl-idene)amino]-benz-yl}imino-meth-yl)phenol.
| S-EPMC3414937 | biostudies-literature
Unknown 2-((E)-{4-[Bis(4-eth-oxy-phen-yl)amino]-phen-yl}imino-meth-yl)phenol.
| S-EPMC3998452 | biostudies-literature
Unknown 2-[(4-Meth-oxy-benz-yl)imino-meth-yl]phenol.
| S-EPMC3011435 | biostudies-literature