Browse
Submit Data
Databases
API
Help

Dataset Information

22 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

2-[5-Methyl-2-(propan-2-yl)phen-oxy]-N'-{2-[5-methyl-2-(propan-2-yl)phen-oxy]acet-yl}acetohydrazide.

ABSTRACT: The complete mol-ecule of the title compound, C(24)H(32)N(2)O(4), is generated by a crystallographic inversion center. The 1,2-diethyl-hydrazine moiety is nearly planar, with a maximum deviation of 0.024 (1) Å, and is inclined at a dihedral angle of 54.20 (4)° with the phenyl ring. In the crystal, [001] chains are formed, with adjacent mol-ecules in the chain linked by pair of inter-molecular N-H⋯O hydrogen bonds, generating R(2) (2)(10) ring motifs. Inter-molecular C-H⋯O hydrogen bonds and C-H⋯π inter-actions are also observed.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3200946 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

2-(4-Chloro-phen-oxy)-N'-[2-(4-chloro-phen-oxy)acet-yl]acetohydrazide monohydrate.

Project description:In the title compound, C(16)H(14)Cl(2)N(2)O(4)·H(2)O, the hydrazine and water mol-ecules are both located on twofold axes. The C-N-N-C torsion angle is -72.66?(1)° and the dihedral angle between the two benzene rings is 67.33?(1)°. In the crystal, mol-ecules are linked into a layer structure by a combination of O-H?O, N-H?O and C-H?O hydrogen bonds. Adjacent layers are linked into a three-dimensional network by Cl?Cl inter-actions [3.400?(2)?Å]. C-H?? inter-actions are also observed.

| S-EPMC3009049 | biostudies-literature

N-(4-Methyl-phen-yl)-N-{[(2-nitro-phen-yl)acet-yl]-oxy}benzamide.

Project description:In the title mol-ecule, C(22)H(18)N(2)O(5), the nitro-substituted benzene ring makes dihedral angles of 71.56?(1)° with the benzoyl ring and 16.28?(1)° with the methyl-substituted benzene ring. The crystal structure features C-H?O inter-actions, which generate chains.

| S-EPMC3470341 | biostudies-literature

2-(4-Methyl-phen-oxy)acetohydrazide.

Project description:In the title compound, C(9)H(12)N(2)O(2), the acetohydrazide group is approximately planar [maximum deviation = 0.034?(2)?Å]. In the crystal, mol-ecules are linked via inter-molecular N-H?O, N-H?N and C-H?O hydrogen bonds into infinite two-dimensional networks parallel to (001).

| S-EPMC3050200 | biostudies-literature

1,3-Bis{[(4-methyl-phen-yl)sulfon-yl]-oxy}propan-2-yl 4-methyl-benzene-sulfonate.

Project description:In the title sulfonate derivative, C(24)H(26)O(9)S(3), all atoms apart from those of one of the 4-methyl-benzene-sulfonate residues lie approximately in a disc; the dihedral angles between the approximately orthogonal benzene ring and those in the plane are 74.53 (9) and 67.79 (11)°. In the crystal, mol-ecules are consolidated into the three-dimensional architecture by C-H⋯O inter-actions. One of the 4-methyl-benzene-sulfonate residues is disordered over two almost parallel positions; the major component refined to a site-occupancy factor of 0.918 (2).

| S-EPMC3297952 | biostudies-literature

2-(Meth-oxy-imino)-2-{2-[(2-methyl-phenoxy)meth-yl]phen-yl}acetohydrazide.

Project description:In the title mol-ecule, C(17)H(19)N(3)O(3), the dihedral angle between the two benzene rings is 57.17 (5)°. In the crystal, N-H⋯O and N-H⋯N hydrogen bonds connect mol-ecules to form chains along [001]. In addition, a weak C-H⋯π inter-action is observed.

| S-EPMC3414344 | biostudies-literature

2-(4-Methyl-phen-yl)acetohydrazide.

Project description:In the title compound, C9H12N2O, the dihedral angle between the benzene ring and the mean plane of the acetohydrazide group is 88.2?(7)°. In the crystal, N-H?O hydrogen bonds and weak C-H?O inter-actions link the mol-ecules into infinite ribbons along [001].

| S-EPMC3589041 | biostudies-literature

(E)-2-(4-Chloro-phen-oxy)-N'-(pyridin-4-yl-methyl-idene)acetohydrazide.

Project description:In the title compound, C14H12ClN3O2, the acyl-hydrazone base [C(=O)-N-N=C] is essentially planar, with an r.m.s. deviation of 0.0095?Å, and makes a dihedral angle of 12.52?(10)°with the pyridine ring. In the crystal, molecules are linked via pairs of N-H?O hydrogen bonds, forming inversion dimers with an R2(2)(8) graph-set motif. The dimers are linked via C-H?? interactions forming chains along [101].

| S-EPMC3588333 | biostudies-literature

2-(2-Methyl-anilino)-N'-(propan-2-yl-idene)acetohydrazide.

Project description:The conformation of the title compound, C(12)H(17)N(3)O, is consolidated by an intra-molecular N-H⋯O hydrogen bond, generating an S(5) ring. In the crystal, inversion dimers linked by pairs of N-H⋯O inter-actions occur, resulting in R(2) (2)(8) ring motifs.

| S-EPMC2970964 | biostudies-literature

[2-Acet-oxy-3-(naphthalen-1-yl-oxy)prop-yl](propan-2-yl)aza-nium chloride monohydrate.

Project description:The title compound, C18H24NO3 (+)·Cl(-)·H2O, was synthesized by the reaction of propranolol hydro-chloride with acetyl chloride in chloro-form followed by slow evaporation in air. In the cation, the dihedral angle between the planes of the naphthalene ring system and the acetate group is 71.1?(2)°. An intra-molecular N-H?O hydrogen bond results in the formation of a non-planar pseudo-ring, with the ether O and the H atom displaced by -1.328?(2) and 0.65?Å, respectively, from the plane of the other ring atoms. The cation and anion are linked by an N-H?Cl hydrogen bond. The water molecule is linked to a methyl H atom by C-H?O hydrogen bond.

| S-EPMC3629540 | biostudies-literature

Methyl 2-{N-[2-(2,4-dichloro-phen-oxy)acet-yl]-4-[(4,6-dimeth-oxy-pyrimidin-2-yl)-oxy]anilino}propano-ate.

Project description:In the title mol-ecule, C(24)H(23)Cl(2)N(3)O(7), the central benzene ring forms dihedral angles of 65.71?(1) and 44.42?(1)° with the pyrimidine ring and the terminal benzene ring, respectively. In the crystal, molecules are linked via C-H?O hydrogen bonds.

| S-EPMC3393314 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data