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(E)-2-(4-Chloro-phen-oxy)-N'-(pyridin-4-yl-methyl-idene)acetohydrazide.

ABSTRACT: In the title compound, C14H12ClN3O2, the acyl-hydrazone base [C(=O)-N-N=C] is essentially planar, with an r.m.s. deviation of 0.0095?Å, and makes a dihedral angle of 12.52?(10)°with the pyridine ring. In the crystal, molecules are linked via pairs of N-H?O hydrogen bonds, forming inversion dimers with an R2(2)(8) graph-set motif. The dimers are linked via C-H?? interactions forming chains along [101].

SUBMITTER: Rao XJ

PROVIDER: S-EPMC3588333 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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(E)-2-(4-Chloro-phen-oxy)-N'-(pyridin-4-yl-methyl-idene)acetohydrazide.

Rao Xiao-Jin XJ Wu Wen-Shi WS Li Chuan-Hui CH Huang Yu-Min YM

Acta crystallographica. Section E, Structure reports online 20121208 Pt 1

In the title compound, C14H12ClN3O2, the acyl-hydrazone base [C(=O)-N-N=C] is essentially planar, with an r.m.s. deviation of 0.0095 Å, and makes a dihedral angle of 12.52 (10)°with the pyridine ring. In the crystal, molecules are linked via pairs of N-H⋯O hydrogen bonds, forming inversion dimers with an R2(2)(8) graph-set motif. The dimers are linked via C-H⋯π interactions forming chains along [101]. ...[more]

PMID: 23476415

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