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(Z)-Methyl 2-[(4-bromo-2-formyl-phen-oxy)meth-yl]-3-o-tolyl-acrylate.

ABSTRACT: In the title compound, C(19)H(17)BrO(4), the dihedral angle between the two benzene rings is 82.1?(1)°. The mol-ecular structure is stabilized by an intra-molecular C-H?O hydrogen bond which generates an S(7) ring motif. The crystal packing is stabilized by inter-molecular C-H?O hydrogen bonds and C-H?? inter-actions. Inter-molecular C-H?O inter-actions are involved in the formation of centrosymmetric R(2) (2)(16) dimers, which are connected into supra-molecular tapes running along the [100] direction.

SUBMITTER: Vijayakumar S

PROVIDER: S-EPMC3201264 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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(Z)-Methyl 2-[(4-bromo-2-formyl-phen-oxy)meth-yl]-3-o-tolyl-acrylate.

Vijayakumar S S Madhanraj R R Murugavel S S Selvakumar R R Bakthadoss M M

Acta crystallographica. Section E, Structure reports online 20110920 Pt 10

In the title compound, C(19)H(17)BrO(4), the dihedral angle between the two benzene rings is 82.1 (1)°. The mol-ecular structure is stabilized by an intra-molecular C-H⋯O hydrogen bond which generates an S(7) ring motif. The crystal packing is stabilized by inter-molecular C-H⋯O hydrogen bonds and C-H⋯π inter-actions. Inter-molecular C-H⋯O inter-actions are involved in the formation of centrosymmetric R(2) (2)(16) dimers, which are connected into supra-molecular tapes running along the [100] dir ...[more]

PMID: 22065120

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