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(Z)-Methyl 3-(2,4-dichloro-phen-yl)-2-[(2-formyl-phen-oxy)meth-yl]acrylate.

ABSTRACT: In the title compound, C(18)H(14)Cl(2)O(4), the mean planes of the methyl acrylate unit and the phenyl ring of the benzaldehyde are approximately orthogonal to each other, making a dihedral angle of 83.31?(6)°. The O atom of the aldehyde group is displaced significantly from the phenyl ring plane by 0.226?(2)?Å. The methyl acrylate group adopts an E conformation. In the crystal, inversion dimers linked by pairs of C-H?O hydrogen bonds generate R(2) (2)(24) loops.

SUBMITTER: Gangadharan R

PROVIDER: S-EPMC3201315 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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(Z)-Methyl 3-(2,4-dichloro-phen-yl)-2-[(2-formyl-phen-oxy)meth-yl]acrylate.

Gangadharan Rajeswari R Sethusankar K K Selvakumar Raman R Bakthadoss Manickam M

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

In the title compound, C(18)H(14)Cl(2)O(4), the mean planes of the methyl acrylate unit and the phenyl ring of the benzaldehyde are approximately orthogonal to each other, making a dihedral angle of 83.31 (6)°. The O atom of the aldehyde group is displaced significantly from the phenyl ring plane by 0.226 (2) Å. The methyl acrylate group adopts an E conformation. In the crystal, inversion dimers linked by pairs of C-H⋯O hydrogen bonds generate R(2) (2)(24) loops. ...[more]

PMID: 22058801

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