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2,6,6-Trimethyl-cyclo-hexene-1-carbaldehyde oxime.

ABSTRACT: In the crystal of the title compound C(10)H(17)NO, synthesized by the reaction of ?-cyclo-citral with hydroxyl-amine hydro-chloride, inversion-related mol-ecules are linked by a pair of O-H?N hydrogen-bonding inter-actions between the oxime functionalities, forming R(2) (2)(6) loops. The molecular conformation is stabilized by intra-molecular methyl C-H?N inter-actions. The cyclohexene ring has the typical half-chair conformation.

SUBMITTER: Parthasarathy R

PROVIDER: S-EPMC3201277 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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2,6,6-Trimethyl-cyclo-hexene-1-carbaldehyde oxime.

Parthasarathy Rajasekaran R Jenniefer Samson Jegan SJ Muthiah Packianathan Thomas PT Sulochana Nagarajan N

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

In the crystal of the title compound C(10)H(17)NO, synthesized by the reaction of β-cyclo-citral with hydroxyl-amine hydro-chloride, inversion-related mol-ecules are linked by a pair of O-H⋯N hydrogen-bonding inter-actions between the oxime functionalities, forming R(2) (2)(6) loops. The molecular conformation is stabilized by intra-molecular methyl C-H⋯N inter-actions. The cyclohexene ring has the typical half-chair conformation. ...[more]

PMID: 22065695

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