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N'-[(E)-2-Chloro-benzyl-idene]-2-[(1,3,4-thia-diazol-2-yl)sulfan-yl]acetohydrazide.

ABSTRACT: In the title compound, C(11)H(9)ClN(4)OS(2), the thia-diazole and chloro-phenyl rings are oriented at an angle of 43.1?(1)°. The sum of the bond angles around the amide N atom (359.8°) of the acetohydrazide group is in accordance with a model of sp(2) hybridization. In the crystal, inversion dimers linked by pairs of N-H?O hydrogen bonds generate R(2) (2)(8) loops. Weak C-H?? inter-actions also occur.

SUBMITTER: Mohan S

PROVIDER: S-EPMC3201361 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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N'-[(E)-2-Chloro-benzyl-idene]-2-[(1,3,4-thia-diazol-2-yl)sulfan-yl]acetohydrazide.

Mohan S S Ananthan S S Ramesh P P Saravanan D D Ponnuswamy M N MN

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

In the title compound, C(11)H(9)ClN(4)OS(2), the thia-diazole and chloro-phenyl rings are oriented at an angle of 43.1 (1)°. The sum of the bond angles around the amide N atom (359.8°) of the acetohydrazide group is in accordance with a model of sp(2) hybridization. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R(2) (2)(8) loops. Weak C-H⋯π inter-actions also occur. ...[more]

PMID: 22058758

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