Browse
Submit Data
Databases
API
Help

Dataset Information

19 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

N'-(4-Chloro-benzyl-idene)-2-[4-(methyl-sulfan-yl)phen-yl]acetohydrazide.

ABSTRACT: In the title compound, C(16)H(15)ClN(2)OS, the hydrazine group is twisted slightly: the C-N-N-C torsion angle is 175.46?(13)°. The dihedral angle between the two terminal aromatic rings is 87.01?(8)°. In the crystal, inversion dimers linked by pairs of N-H?O hydrogen bonds generate R(2) (2)(8) loops. The dimers are further linked by weak C-H?? inter-actions.

SUBMITTER: Fun HK

PROVIDER: S-EPMC3247585 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

N'-(4-Chloro-benzyl-idene)-2-[4-(methyl-sulfan-yl)phen-yl]acetohydrazide.

Fun Hoong-Kun HK Hemamalini Madhukar M Sumangala V V Prasad D Jagadeesh DJ Poojary Boja B

Acta crystallographica. Section E, Structure reports online 20111005 Pt 11

In the title compound, C(16)H(15)ClN(2)OS, the hydrazine group is twisted slightly: the C-N-N-C torsion angle is 175.46 (13)°. The dihedral angle between the two terminal aromatic rings is 87.01 (8)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds generate R(2) (2)(8) loops. The dimers are further linked by weak C-H⋯π inter-actions. ...[more]

PMID: 22219890

Similar Datasets

N'-Benzyl-idene-2-chloro-N-(4-chloro-phen-yl)acetohydrazide.

Project description:In the title compound, C15H12Cl2N2O, the atoms not making up the chloro-benzene ring are approximately coplanar (r.m.s. deviation = 0.073?Å). The dihedral angle between these 13 atoms and the chloro-benzene ring is 67.37?(10)°. The C=O and Csp (2)-Cl groups are almost eclipsed [Cl-C-C=O = -6.5?(3)°]. In the crystal, C(6) chains linked by C-H?O hydrogen bonds result in [100] chains.

| S-EPMC3914076 | biostudies-literature

N'-[(E)-2-Chloro-benzyl-idene]-2-[(1,3,4-thia-diazol-2-yl)sulfan-yl]acetohydrazide.

Project description:In the title compound, C(11)H(9)ClN(4)OS(2), the thia-diazole and chloro-phenyl rings are oriented at an angle of 43.1?(1)°. The sum of the bond angles around the amide N atom (359.8°) of the acetohydrazide group is in accordance with a model of sp(2) hybridization. In the crystal, inversion dimers linked by pairs of N-H?O hydrogen bonds generate R(2) (2)(8) loops. Weak C-H?? inter-actions also occur.

| S-EPMC3201361 | biostudies-literature

(E)-N'-(4-Fluoro-benzyl-idene)-2-(3-methyl-phen-yl)acetohydrazide.

Project description:In the title compound, C16H15FN2O, the dihedral angles between the benzene rings are74.7(8), 74.1?(1), 74.2?(7) and 74.3?(5)° in the four independent mol-ecules in the asymmetric unit. In the crystal, N-H-O hydrogen bonds involving the hydrazide and acetyl groups, which form R2(2)(18) ring motifs, link the mol-ecules into dimers, which form columns along [010].

| S-EPMC3588440 | biostudies-literature

N-[(E)-2-Chloro-benzyl-idene]-3-(4-methyl-benzyl-sulfan-yl)-5-(3,4,5-trimethoxy-phen-yl)-4H-1,2,4-triazol-4-amine.

Project description:In the title compound, C(26)H(25)ClN(4)O(3)S, the acyclic imine group exhibits an E configuration. The triazole ring is oriented at dihedral angles of 53.84?(2), 70.77?(1) and 32.59?(3)° with respect to the benzene rings of the 2-chloro-benzyl-idene, 4-methyl-benzyl-sulfanyl and 3,4,5-trimethoxy-phenyl groups, respectively. The crystal packing is stabilized by weak inter-molecular C-H?N, C-H?S and C-H?? inter-actions.

| S-EPMC2968782 | biostudies-literature

(E)-2-(4-Chloro-phen-oxy)-N'-(pyridin-4-yl-methyl-idene)acetohydrazide.

Project description:In the title compound, C14H12ClN3O2, the acyl-hydrazone base [C(=O)-N-N=C] is essentially planar, with an r.m.s. deviation of 0.0095?Å, and makes a dihedral angle of 12.52?(10)°with the pyridine ring. In the crystal, molecules are linked via pairs of N-H?O hydrogen bonds, forming inversion dimers with an R2(2)(8) graph-set motif. The dimers are linked via C-H?? interactions forming chains along [101].

| S-EPMC3588333 | biostudies-literature

N'-[1-(4-Chloro-phen-yl)ethyl-idene]acetohydrazide.

Project description:In the title compound, C(10)H(11)ClN(2)O, the dihedral angle between the acetohydrazide group and the aromatic ring is 33.76?(9)°. In the crystal, inversion dimers linked by pairs of N-H?O hydrogen bonds generate R(2) (2)(8) loops.

| S-EPMC3009114 | biostudies-literature

N'-[Bis(benzyl-sulfan-yl)methyl-idene]benzohydrazide.

Project description:In the title hydrazonodithio-ate, C(21)H(19)N(3)OS(2), the amide group is twisted out of the plane through the S(2)C=N atoms: the C-N-N-C torsion angle is 139.71?(13)°. The pyridine ring forms dihedral angles of 52.96?(8) and 86.46?(8)° with the phenyl rings, and the latter are approximately orthogonal [dihedral angle = 76.42?(9)°]. Supra-molecular chains sustained by N-H?O hydrogen bonds and propagated by glide symmetry along the c axis are found in the crystal structure. The chains are consolidated into a three-dimensional architecture by C-H?O and C-H?N inter-actions.

| S-EPMC3379243 | biostudies-literature

{5-Chloro-2-[(4-chloro-benzyl-idene)-amino]-phen-yl}(phen-yl)methanone.

Project description:In the title compound, C(20)H(13)Cl(2)NO, the C=N bond adopts an E conformation. The chloro-substituted rings form a dihedral angle of 11.99?(9)° with each other and form dihedral angles of 74.95?(9) and 83.26?(10)° with the unsubstituted ring. In the crystal, mol-ecules are connected into dimers by pairs of weak C-H?O hydrogen bonds and the dimers are arranged in columns parallel to the a axis.

| S-EPMC3295436 | biostudies-literature

N'-(4-Fluoro-benzyl-idene)-2-(4-fluoro-phen-yl)acetohydrazide.

Project description:In the title compound, C(15)H(12)F(2)N(2)O, the dihedral angle between the two benzene rings is 48.73?(8)°. The hydrazine group is twisted slightly, with a C-N-N-C torsion angle of 172.48?(12)°. In the crystal, mol-ecules are connected by strong N-H?O and weak C-H?O hydrogen bonds, forming supra-molecular chains along the c axis. The structure is consolidated by ?-? [centroid-centroid separation = 3.6579?(10)?Å] and C-H?? inter-actions.

| S-EPMC3247574 | biostudies-literature

4-Methyl-1-[4-(methyl-sulfan-yl)benzyl-idene]thio-semicarbazide.

Project description:The title compound, C(10)H(13)N(3)S(2), is roughly planar (r.m.s. deviation = 0.086?Å). In the crystal, N-H?S hydrogen bonds link the mol-ecules into (001) sheets.

| S-EPMC3213514 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data