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(4-Bromo-2-{[2-(morpholin-4-yl)ethyl-imino]-meth-yl}phenolato)dioxido-vanadium(V).

ABSTRACT: In the title mononuclear dioxidovanadium(V) complex, [V(C(13)H(16)BrN(2)O(2))O(2)], the V(V) atom is five-coordinated by one phenolate O, one imine N and one morpholine N atom of the Schiff base ligand, and by two oxide O atoms, forming a distorted square-pyramidal geometry. In the crystal, weak C-H?O inter-actions and a short Br?Br contact [3.4597?(12)?Å] are observed.

SUBMITTER: Wang CY

PROVIDER: S-EPMC3201471 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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(4-Bromo-2-{[2-(morpholin-4-yl)ethyl-imino]-meth-yl}phenolato)dioxido-vanadium(V).

Wang Chen-Yi CY Wu Xiang X Cao Feng F Yuan Cai-Jun CJ

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

In the title mononuclear dioxidovanadium(V) complex, [V(C(13)H(16)BrN(2)O(2))O(2)], the V(V) atom is five-coordinated by one phenolate O, one imine N and one morpholine N atom of the Schiff base ligand, and by two oxide O atoms, forming a distorted square-pyramidal geometry. In the crystal, weak C-H⋯O inter-actions and a short Br⋯Br contact [3.4597 (12) Å] are observed. ...[more]

PMID: 22065600

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