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{4-Bromo-2-[2-(isopropyl-amino)ethyl-imino-meth-yl]phenolato}thio-cyanato-copper(II).

ABSTRACT: In the title mononuclear Schiff base copper(II) complex, [Cu(C(12)H(16)BrN(2)O)(NCS)], the Cu(II) ion is coordinated by two N atoms and one O atom from a Schiff base ligand, and by one N atom from a thio-cyanate anion, giving a square-planar geometry. There are long-range inter-actions between the Cu atom and S [3.151?(5)?Å] and Br [3.929?(5)?Å] atoms above and below the square plane.

SUBMITTER: Ma JY

PROVIDER: S-EPMC2961070 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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{4-Bromo-2-[2-(isopropyl-amino)ethyl-imino-meth-yl]phenolato}thio-cyanato-copper(II).

Ma Jun-Ying JY He Yin-Ting YT

Acta crystallographica. Section E, Structure reports online 20080418 Pt 5

In the title mononuclear Schiff base copper(II) complex, [Cu(C(12)H(16)BrN(2)O)(NCS)], the Cu(II) ion is coordinated by two N atoms and one O atom from a Schiff base ligand, and by one N atom from a thio-cyanate anion, giving a square-planar geometry. There are long-range inter-actions between the Cu atom and S [3.151 (5) Å] and Br [3.929 (5) Å] atoms above and below the square plane. ...[more]

PMID: 21202223

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