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2-Azido-1-(3,6-dichloro-9H-fluoren-1-yl)ethanone.


ABSTRACT: In the title compound, C(15)H(9)Cl(2)N(3)O, an intra-molecular C-H?O inter-action generates an S(7) ring motif. The cyclo-penta-1,3-diene ring forms dihedral angles of 1.93?(6) and 2.78?(6)° with its attached benzene rings. In the crystal, mol-ecules are linked by C-H?N and C-H?O hydrogen bonds, thereby forming layers lying parallel to the ac plane. The crystal also features a ?-? inter-action with a centroid-centroid distance of 3.5612?(6)?Å.

SUBMITTER: Fun HK 

PROVIDER: S-EPMC3201472 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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2-Azido-1-(3,6-dichloro-9H-fluoren-1-yl)ethanone.

Fun Hoong-Kun HK   Chia Tze Shyang TS   Kayarmar Reshma R   Dinesha   Nagaraja G K GK  

Acta crystallographica. Section E, Structure reports online 20110917 Pt 10


In the title compound, C(15)H(9)Cl(2)N(3)O, an intra-molecular C-H⋯O inter-action generates an S(7) ring motif. The cyclo-penta-1,3-diene ring forms dihedral angles of 1.93 (6) and 2.78 (6)° with its attached benzene rings. In the crystal, mol-ecules are linked by C-H⋯N and C-H⋯O hydrogen bonds, thereby forming layers lying parallel to the ac plane. The crystal also features a π-π inter-action with a centroid-centroid distance of 3.5612 (6) Å. ...[more]

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