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Tetra-kis(diethyl ether)tetra-?(4)-oxido-octa-kis-(penta-fluoro-phen-yl)octa-zinc.

ABSTRACT: Mol-ecules of the title compound, [Zn(8)(C(6)F(5))(8)O(4)(C(4)H(10)O)(4)], are located on a special position of site symmetry [Formula: see text]. As a result, there is just one quarter-mol-ecule in the asymmetric unit. The title compound features a Zn(4)O(4) cube. Each Zn atom in the cube carries a pentafluorophenyl substituent. Each O atom is bonded to a further Zn atom, which is connected to a pentafluorophenyl substituent and the O atom of a diethyl ether mol-ecule. All ether C atoms are disordered over two sets of sites with a site occupation factor of 0.51?(2) for the major occupied site.

SUBMITTER: Franz D

PROVIDER: S-EPMC3201485 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Tetra-kis(diethyl ether)tetra-μ(4)-oxido-octa-kis-(penta-fluoro-phen-yl)octa-zinc.

Franz Daniel D Lerner Hans-Wolfram HW Bolte Michael M

Acta crystallographica. Section E, Structure reports online 20110917 Pt 10

Mol-ecules of the title compound, [Zn(8)(C(6)F(5))(8)O(4)(C(4)H(10)O)(4)], are located on a special position of site symmetry [Formula: see text]. As a result, there is just one quarter-mol-ecule in the asymmetric unit. The title compound features a Zn(4)O(4) cube. Each Zn atom in the cube carries a pentafluorophenyl substituent. Each O atom is bonded to a further Zn atom, which is connected to a pentafluorophenyl substituent and the O atom of a diethyl ether mol-ecule. All ether C atoms are dis ...[more]

PMID: 22064629

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