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Triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetra-kis-(penta-fluoro-phen-yl)borate.

ABSTRACT: In the title molecular salt, C36H30NP2(+)·C24BF20(-), the P-N bond lengths in the cation are equal [1.573?(2) and 1.572?(2)?Å], indicating a resonance structure and the P-N-P bond angle is 144.79?(12)°. In the crystal, weak C-H?F interactions link the cations and the anions.

SUBMITTER: Vanysek P

PROVIDER: S-EPMC3588361 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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Triphenyl[(triphenylphosphoranylidene)amino]phosphonium tetra-kis-(penta-fluoro-phen-yl)borate.

Vanýsek Petr P Zheng Chong C

Acta crystallographica. Section E, Structure reports online 20121215 Pt 1

In the title molecular salt, C36H30NP2(+)·C24BF20(-), the P-N bond lengths in the cation are equal [1.573 (2) and 1.572 (2) Å], indicating a resonance structure and the P-N-P bond angle is 144.79 (12)°. In the crystal, weak C-H⋯F interactions link the cations and the anions. ...[more]

PMID: 23476468

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