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Catena-Poly[[bis-(3-methyl-benzoato-?O,O')lead(II)]-?-4,4'-bipyridine-?N:N'].

ABSTRACT: In the title complex, [Pb(C(8)H(7)O(2))(2)(C(10)H(8)N(2))](n), the Pb(II) atom is located on a twofold rotation axis and is six-coordinated by four carboxyl-ate O atoms from two 3-methyl-benzoate ligands and two N atoms from two 4,4'-bipyridine (4,4'-bpy) ligands, displaying a hemi-directed coordination. The 4,4'-bpy ligand has an inversion center at the mid-point of the central C-C bond. The Pb(II) atoms are linked by bidentate bridging 4,4'-bpy into a chain along [101]. These chains are further connected into layers via C-H?O hydrogen bonds.

SUBMITTER: Xie JY 

PROVIDER: S-EPMC3201505 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-(3-methyl-benzoato-κO,O')lead(II)]-μ-4,4'-bipyridine-κN:N'].

Xie Jian-Ying JY   Huang Fu F  

Acta crystallographica. Section E, Structure reports online 20110903 Pt 10

In the title complex, [Pb(C(8)H(7)O(2))(2)(C(10)H(8)N(2))](n), the Pb(II) atom is located on a twofold rotation axis and is six-coordinated by four carboxyl-ate O atoms from two 3-methyl-benzoate ligands and two N atoms from two 4,4'-bipyridine (4,4'-bpy) ligands, displaying a hemi-directed coordination. The 4,4'-bpy ligand has an inversion center at the mid-point of the central C-C bond. The Pb(II) atoms are linked by bidentate bridging 4,4'-bpy into a chain along [101]. These chains are furthe  ...[more]

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