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Trichlorido-1?Cl,2?Cl-(2,6-dimethyl-phenolato-2?O)-?-oxido-bis{1,2(?)-2,3,4,5-tetra-methyl-1-[4-(trimethyl-silyl)phen-yl]cyclo-penta-dien-yl}dititanium(IV).

ABSTRACT: The title dinuclear titanocene, [Ti(2)(C(8)H(9)O)(C(18)H(25)Si)(2)Cl(3)O], contains one Ti atom tetra-hedrally coordinated by two Cl atoms, a bridging O atom and the substituted cyclo-penta-dienyl ligand, and another Ti atom tetra-hedrally coordinated by a Cl atom, a bridging O atom, the 2,6-dimethyl-phenolate ligand and the substituted cyclo-penta-dienyl ligand. The bridging O atom lies on a twofold rotation axis.

SUBMITTER: Luo X

PROVIDER: S-EPMC3201525 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Trichlorido-1κCl,2κCl-(2,6-dimethyl-phenolato-2κO)-μ-oxido-bis{1,2(η)-2,3,4,5-tetra-methyl-1-[4-(trimethyl-silyl)phen-yl]cyclo-penta-dien-yl}dititanium(IV).

Luo Xuyang X Wu Qiaolin Q Mu Ying Y

Acta crystallographica. Section E, Structure reports online 20110914 Pt 10

The title dinuclear titanocene, [Ti(2)(C(8)H(9)O)(C(18)H(25)Si)(2)Cl(3)O], contains one Ti atom tetra-hedrally coordinated by two Cl atoms, a bridging O atom and the substituted cyclo-penta-dienyl ligand, and another Ti atom tetra-hedrally coordinated by a Cl atom, a bridging O atom, the 2,6-dimethyl-phenolate ligand and the substituted cyclo-penta-dienyl ligand. The bridging O atom lies on a twofold rotation axis. ...[more]

PMID: 22064795

Similar Datasets

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