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Hydrogen-bonding 2D metal-organic solids as highly robust and efficient heterogeneous green catalysts for Biginelli reaction.

ABSTRACT: Two new Zn(II) and Cd(II) MOFs have been synthesized. These MOFs have been applied as heterogeneous catalysts for the green synthesis of a variety of dihydropyrimidinone derivatives through the Biginelli reaction and the desired products were obtained in high yields with short reaction time under mild solvent- free conditions. Moreover, the MOF catalysts may be readily recovered after the reaction and reused for many cycles.

SUBMITTER: Li P

PROVIDER: S-EPMC3203686 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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Hydrogen-bonding 2D metal-organic solids as highly robust and efficient heterogeneous green catalysts for Biginelli reaction.

Li Peng P Regati Sridhar S Butcher Raymond J RJ Arman Hadi D HD Chen Zhenxia Z Xiang Shengchang S Chen Banglin B Zhao Cong-Gui CG

Tetrahedron letters 20111101 47

Two new Zn(II) and Cd(II) MOFs have been synthesized. These MOFs have been applied as heterogeneous catalysts for the green synthesis of a variety of dihydropyrimidinone derivatives through the Biginelli reaction and the desired products were obtained in high yields with short reaction time under mild solvent- free conditions. Moreover, the MOF catalysts may be readily recovered after the reaction and reused for many cycles. ...[more]

PMID: 22043110

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