Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

A combination of hard and soft templating for the fabrication of silica hollow microcoils with nanostructured walls.

ABSTRACT: Hollow silica microcoils have been prepared by using functionalized carbon microcoils as hard templates and surfactant or amphiphilic dye aggregates as soft templates. The obtained materials have been characterized by electron and optical microscopy, nitrogen sorption and small angle X-ray scattering. The obtained hollow microcoils resemble the original hard templates in shape and size. Moreover, they have mesoporous walls (pore size ? 3 nm) with some domains where pores are ordered in a hexagonal array, originated from surfactant micelles. The obtained silica microcoils also show preferential adsorption of cationic fluorescent dyes. A mechanism for the formation of silica microcoils is proposed.

SUBMITTER: Rodriguez-Abreu C

PROVIDER: S-EPMC3211418 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

A combination of hard and soft templating for the fabrication of silica hollow microcoils with nanostructured walls.

Rodriguez-Abreu Carlos C Vilanova Neus N Solans Conxita C Ujihara Masaki M Imae Toyoko T López-Quintela Arturo A Motojima Seiji S

Nanoscale research letters 20110413 1

Hollow silica microcoils have been prepared by using functionalized carbon microcoils as hard templates and surfactant or amphiphilic dye aggregates as soft templates. The obtained materials have been characterized by electron and optical microscopy, nitrogen sorption and small angle X-ray scattering. The obtained hollow microcoils resemble the original hard templates in shape and size. Moreover, they have mesoporous walls (pore size ≈ 3 nm) with some domains where pores are ordered in a hexagon ...[more]

PMID: 21711843

Similar Datasets

Bottom-up Fabrication of Graphene on Silicon/Silica Substrate via a Facile Soft-hard Template Approach.

Project description:In this work, a novel soft-hard template method towards the direct fabrication of graphene films on silicon/silica substrate is developed via a tri-constituent self-assembly route. Using cetyl trimethyl ammonium bromide (CTAB) as a soft template, silica (SiO2) from tetramethoxysilane as a hard template, and pyrene as a carbon source, the self-assembly process allows the formation of a sandwich-like SiO2/CTAB/pyrene composite, which can be further converted to high quantity graphene films with a thickness of ~1 nm and a size of over 5 μm by thermal treatment. The morphology and thickness of the graphene films can be effectively controlled through the adjustment of the ratio of pyrene to CTAB. Furthermore, a high nonlinear refractive index n2 of ~10(-12) m(2) W(-1) is measured from graphene/silica hybrid film, which is six orders of magnitude larger than that of silicon and comparable to the graphene from chemical vapor deposition process.

| S-EPMC4550833 | biostudies-literature

MOF-Based Nanotubes to Hollow Nanospheres through Protein-Induced Soft-Templating Pathways.

Project description:A controllable and facile strategy is established for constructing metal-organic frameworks-based (MOF-based) hollow composites via a protein-induced soft-templating pathway. Using metal-sodium deoxycholate hydrogel as soft-template, nanotubes are gained while the protein is absent. With the presence of protein, hollow nanospheres structure are prepared by changing the amount of protein. To verify the universality of the proposed pathway, two kinds of proteins (Burkholderia cepacia lipase and penicillin G acylase) and three kinds of MOF (ZIF-8, ZIF-67, and Fe-MOF) are adopted as model proteins and materials, and the obtained protein-containing composites (named protein@H-MOF) possess high bioactivity and stability. This proposed strategy provides a facile method for preparing MOF-based composites under mild conditions, facilitating the applications of MOF in the fields of biocatalyst construction, biomolecule encapsulation, and drug delivery.

| S-EPMC6425429 | biostudies-literature

Mesoporous silica films as hard templates for electrodeposition of nanostructured gold.

Project description:Metallic nanostructures have widespread applications in fields including materials science, electronics and catalysis. Mesoporous silica films synthesised by evaporation induced self-assembly and electrochemically assisted self-assembly with pores below 10 nm were used as hard templates for the electrodeposition of Au nanostructures. Electrodeposition conditions were optimised based on pore orientation and size. The growth of nanostructures was initiated at the electrode surface as confirmed by microscopy. The hard templates and Au electrodeposits were characterised electrochemically as well as with X-ray diffraction, small angle scattering and transmission electron microscopy. Finally, mesoporous silica hard templates were removed by hydrofluoric acid etching and stable Au nanoparticles on different electrode surfaces were achieved.

| S-EPMC9642781 | biostudies-literature

Fabrication of arbitrary three-dimensional suspended hollow microstructures in transparent fused silica glass.

Project description:Fused silica glass is the preferred material for applications which require long-term chemical and mechanical stability as well as excellent optical properties. The manufacturing of complex hollow microstructures within transparent fused silica glass is of particular interest for, among others, the miniaturization of chemical synthesis towards more versatile, configurable and environmentally friendly flow-through chemistry as well as high-quality optical waveguides or capillaries. However, microstructuring of such complex three-dimensional structures in glass has proven evasive due to its high thermal and chemical stability as well as mechanical hardness. Here we present an approach for the generation of hollow microstructures in fused silica glass with high precision and freedom of three-dimensional designs. The process combines the concept of sacrificial template replication with a room-temperature molding process for fused silica glass. The fabricated glass chips are versatile tools for, among other, the advance of miniaturization in chemical synthesis on chip.

| S-EPMC6441035 | biostudies-literature

Fabrication of hard tissue using dental cells derived from hiPSCs

Project description:To analyze the transcriptomic differences between hiPSC and hiPSC-derived dental epithelial cells (hDEC), and between hiPSC and hiPSC-derived dental mesenchymal cells (hDMCs)

2022-12-05 | GSE218926 | GEO

Highly-Controlled Soft-Templating Synthesis of Hollow ZIF-8 Nanospheres for Selective CO<sub>2</sub> Separation and Storage.

Project description:Global warming is an ever-rising environmental concern, and carbon dioxide (CO2) is among its major causes. Different technologies, including adsorption, cryogenic separation, and sequestration, have been developed for CO2 separation and storage/utilization. Among these, carbon capture using nano-adsorbents has the advantages of excellent CO2 separation and storage performance as well as superior heat- and mass-transfer characteristics due to their large surface area and pore volume. In this work, an environmentally friendly, facile, bottom-up synthesis of ZIF-8 hollow nanospheres (with reduced chemical consumption) was developed for selective CO2 separation and storage. During this soft-templating synthesis, a combined effect of ultra-sonication and low-temperature hydrothermal synthesis showed better control over an oil-in-water microemulsion formation and the subsequent growth of large-surface-area hollow ZIF-8 nanospheres having excellent particle size distribution. Systematic studies on the synthesis parameters were also performed to achieve fine-tuning of the ZIF-8 crystallinity, hollow structures, and sphere size. The optimized hollow ZIF-8 nanosphere sample having uniform size distribution exhibited remarkable CO2 adsorption capability (∼2.24 mmol g-1 at 0 °C and 1.75 bar), a CO2/N2 separation selectivity of 12.15, a good CO2 storage capacity (1.5-1.75 wt %), and an excellent cyclic adsorption/desorption performance (up to four CO2 adsorption/desorption cycles) at 25 °C. In addition, the samples showed exceptional structural stability with only ∼15% of overall weight loss up to 600 °C under a nitrogen environment. Therefore, the hollow ZIF-8 nanospheres as well as their highly controlled soft-templating synthesis method reported in this work are useful in the course of the development of nanomaterials with optimized properties for future CO2 capture technologies.

| S-EPMC10326808 | biostudies-literature

Thickness and Sphericity Control of Hollow Hard Silica Shells through Iron (III) Doping: Low Threshold Ultrasound Contrast Agents.

Project description:Silica particles are convenient ultrasound imaging contrast agents because of their long imaging time and ease of modification; however, they require a relatively high insonation power for imaging and have low biodegradability. In this study, 2 μm ultrathin asymmetric hollow silica particles doped with iron (III) (Fe(III)-SiO2) are synthesized to produce biodegradable hard shelled particles with a low acoustic power threshold comparable with commercial soft microbubble contrast agents (Definity) yet with much longer in vivo ultrasound imaging time. Furthermore, high intensity focused ultrasound ablation enhancement with these particles shows a 2.5-fold higher temperature elevation than with Definity at the same applied power. The low power visualization improves utilization of the silica shells as an adjuvant in localized immunotherapy. The data are consistent with asymmetric engineering of hard particle properties that improve functionality of hard versus soft particles.

| S-EPMC8318338 | biostudies-literature

Fabrication and functionalization of 3D-printed soft and hard scaffolds with growth factors for enhanced bioactivity.

Project description:Strategies to improve the acceptance of scaffolds by the body is crucial in tissue engineering (TE) which requires tailoring of the pore structure, mechanical properties and surface characteristics of the scaffolds. In the current study we used a 3-dimensional (3D) printing technique to tailor the pore structure and mechanical properties of (i) nanocellulose based hydrogel scaffolds for soft tissue engineering and (ii) poly lactic acid (PLA) based scaffolds for hard tissue engineering in combination with surface treatment by protein conjugation for tuning the scaffold bioactivity. Dopamine coating of the scaffolds enhanced the hydrophilicity and their capability to bind bioactive molecules such as fibroblast growth factor (FGF-18) for soft TE scaffolds and arginyl glycyl aspartic acid (RGD) peptide for hard TE scaffolds, which was confirmed using MALDI-TOFs. This functionalization approach enhanced the performance of the scaffolds and provided antimicrobial activity indicating that these scaffolds can be used for cartilage or bone regeneration applications. Blood compatibility studies revealed that both the materials were compatible with human red blood cells. Significant enhancement of cell attachment and proliferation confirmed the bioactivity of growth factor functionalized 3D printed soft and hard tissues. This approach of combining 3D printing with biological tuning of the interface is expected to significantly advance the development of biomedical materials related to soft and hard tissue engineering.

| S-EPMC9057203 | biostudies-literature

Fabrication of Functionalized Porous Silica Nanocapsules with a Hollow Structure for High Performance of Toluene Adsorption-Desorption.

Project description:Functionalized mesoporous silicas are an emerging kind of adsorbents for the removal of volatile organic compounds (VOCs). Breaking the limitations of traditional mesoporous silica, in this study, porous silica nanocapsules (PSNs) functionalized with phenyl and n-octyl groups (named as p-PSN and n-PSN, respectively) were developed for the first time. Under dry conditions, the PSNs exhibited highest dynamic adsorption capacity and desorption efficiency among the ever-reported typical adsorbents (i.e., SBA-15, KIT-6, silicalite-1, and activated carbon). Under wet conditions, the functionalized PSNs made up the defects of pure PSNs, displaying excellent hydrophobicity. The Q WET for n-PSN and p-PSN increased by 44 and 76%, respectively, as compared with that of pure PSNs in 50% relative humidity. The Henry constant of static adsorption demonstrated that p-PSN had a better capture ability for toluene, which was owing to the ?-interaction between the phenyl groups and the toluene molecules. In addition, p-PSN showed considerable stability after six consecutive dynamic adsorption-desorption cycles in 50% relative humidity.

| S-EPMC7097888 | biostudies-literature

Nanostructured Polymethylsiloxane/Fumed Silica Blends.

Project description:Polymethylsiloxane (PMS) and fumed silica, alone and in a blended form (1:1 w/w), differently pretreated, hydrated, and treated again, were studied using TEM and SEM, nitrogen adsorption-desorption, 1H MAS and 29Si CP/MAS NMR spectroscopy, infrared spectroscopy, and methods of quantum chemistry. Analysis of the effects of adding water (0-0.5 g of water per gram of solids) to the blends while they are undergoing different mechanical treatment (stirring with weak (~1-2 kg/cm2) and strong (~20 kg/cm2) loading) show that both dry and wetted PMS (as a soft material) can be grafted onto a silica surface, even with weak mechanical loading, and enhanced mechanical loading leads to enhanced homogenization of the blends. The main evidence of this effect is strong nonadditive changes in the textural characteristics, which are 2-3 times smaller than additive those expected. All PMS/nanosilica blends, demonstrating a good distribution of nanosilica nanoparticles and their small aggregates in the polymer matrix (according to TEM and SEM images), are rather meso/microporous, with the main pore-size distribution peaks at R > 10 nm in radius and average <RV> values of 18-25 nm. The contributions of nanopores (R < 1 nm), mesopores (1 nm < R < 25 nm), and macropores (25 nm < R < 100 nm), which are of importance for studied medical sorbents and drug carriers, depend strongly on the types of the materials and treatments, as well the amounts of water added. The developed technique (based on small additions of water and controlled mechanical loading) allows one to significantly change the morphological and textural characteristics of fumed silica (hydrocompaction), PMS (drying-wetting-drying), and PMS/A-300 blends (wetting-drying under mechanical loading), which is of importance from a practical point of view.

| S-EPMC6695803 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data