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N-[Amino-(azido)-meth-ylidene]-4-methyl-benzene-sulfonamide.

ABSTRACT: In the title mol-ecule, C(8)H(10)N(5)O(2)S, the amino-(azido)-methyl and p-toluene-sulfonyl moieties are inclined almost at right angles with respect to each other, making a dihedral angle of 83.49?(6)°. An intra-molecular N-H?O hydrogen bond gives rise to the formation of six-membered ring with graph-set motif S(6). In the crystal, inter-molecular N-H?O hydrogen bonding is responsible for the formation of dimers about inversion centers, which are linked through another N-H?O inter-action along the b axis.

SUBMITTER: Mahmood A

PROVIDER: S-EPMC3213580 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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N-[Amino-(azido)-meth-ylidene]-4-methyl-benzene-sulfonamide.

Mahmood Ayyaz A Khan Islam Ullah IU Arshad Muhammad Nadeem MN Ahmed Jamil J

Acta crystallographica. Section E, Structure reports online 20110723 Pt 8

In the title mol-ecule, C(8)H(10)N(5)O(2)S, the amino-(azido)-methyl and p-toluene-sulfonyl moieties are inclined almost at right angles with respect to each other, making a dihedral angle of 83.49 (6)°. An intra-molecular N-H⋯O hydrogen bond gives rise to the formation of six-membered ring with graph-set motif S(6). In the crystal, inter-molecular N-H⋯O hydrogen bonding is responsible for the formation of dimers about inversion centers, which are linked through another N-H⋯O inter-action along ...[more]

PMID: 22091157

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