Unknown

Dataset Information

0

1,2-Bis[5-(9-ethyl-9H-carbazol-3-yl)-2-methyl-thio-phen-3-yl]-3,3,4,4,5,5-hexa-fluoro-cyclo-pentene.

ABSTRACT: The title compound, C(43)H(32)F(6)N(2)S(2), is a new symmetrical photochromic diaryl-ethene derivative with 9-ethyl-carbazol-3-yl substituents. The mol-ecule adopts a photoactive anti-parallel conformation [Irie (2000). Chem. Rev.100, 1685-1716; Kobatake et al. (2002). Chem. Commun. pp. 2804-2805], with a dihedral angle between the mean planes of the two thio-phene rings of 56.23?(6)°. The distance between the two reactive C atoms is 3.497?(3)?Å. In the crystal, two mol-ecules are associated through a pair of C-H?F inter-molecular hydrogen bonds, forming a centrosymmetric dimer. Dimers are linked by weak ?-? inter-actions [centroid-centroid distance = 3.8872?(13)?Å], forming chains along the c axis.

SUBMITTER: Kubono K 

PROVIDER: S-EPMC3213625 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

1,2-Bis[5-(9-ethyl-9H-carbazol-3-yl)-2-methyl-thio-phen-3-yl]-3,3,4,4,5,5-hexa-fluoro-cyclo-pentene.

Kubono Koji K   Synmyouzu Teruo T   Goto Kenta K   Tsujioka Tsuyoshi T   Tani Keita K  

Acta crystallographica. Section E, Structure reports online 20110730 Pt 8

The title compound, C(43)H(32)F(6)N(2)S(2), is a new symmetrical photochromic diaryl-ethene derivative with 9-ethyl-carbazol-3-yl substituents. The mol-ecule adopts a photoactive anti-parallel conformation [Irie (2000). Chem. Rev.100, 1685-1716; Kobatake et al. (2002). Chem. Commun. pp. 2804-2805], with a dihedral angle between the mean planes of the two thio-phene rings of 56.23 (6)°. The distance between the two reactive C atoms is 3.497 (3) Å. In the crystal, two mol-ecules are associated thr  ...[more]

Similar Datasets

Unknown 3,3,4,4,5,5-Hexa-fluoro-1,2-bis[4-(phenyl-ethyn-yl)phen-yl]-cyclo-pentene.
| S-EPMC2980200 | biostudies-literature
Unknown 3,3,4,4,5,5-Hexa-fluoro-1,2-bis-[5-(2-fluoro-4'-undecyl-oxybiphenyl-4-yl)-2-methyl-3-thien-yl]cyclo-pentene.
| S-EPMC2961548 | biostudies-literature
Unknown 2-(1,2-Dimethyl-1H-indol-3-yl)-1-{5-[3-(1,3-dioxolan-2-yl)phen-yl]-2-methyl-thio-phen-3-yl}-3,3,4,4,5,5-hexa-fluoro-cyclo-pent-1-ene.
| S-EPMC3247444 | biostudies-literature
Unknown 2,5-Bis(9H-carbazol-9-yl)thio-phene.
| S-EPMC2960087 | biostudies-literature
Unknown 1,2-Bis[5-(4-cyano-phen-yl)-2-methyl-3-thien-yl]-3,3,4,4,5,5-hexa-fluoro-cyclo-pent-1-ene: a photochromic diaryl-ethene compound.
| S-EPMC2961168 | biostudies-literature
Unknown 5-n-Butyl-4-[2-(2-ethyl-1-benzothio-phen-3-yl)-3,3,4,4,5,5-hexa-fluoro-cyclo-pent-1-en-1-yl]thio-phene-2-carbaldehyde.
| S-EPMC2959974 | biostudies-literature
Unknown 4-{2-[5-(3,5-Difluoro-phen-yl)-2-methyl-thio-phen-3-yl]-3,3,4,4,5,5-hexa-fluoro-cyclo-pent-1-en-1-yl}-1,5-dimethyl-pyrrole-2-carbonitrile.
| S-EPMC3099757 | biostudies-literature
Unknown 4-(5-{2-[5-(4-Cyano-phen-yl)-3-methyl-thio-phen-2-yl]-3,3,4,4,5,5-hexa-fluoro-cyclo-pent-1-en-1-yl}-4-methyl-thio-phen-2-yl)benzo-nitrile chloro-form hemisolvate.
| S-EPMC3772474 | biostudies-literature
Unknown 1-[5-(3-Chloro-phen-yl)-2-methyl-3-thi-en-yl]-3,3,4,4,5,5-hexa-fluoro-2-(2-methoxy-phen-yl)-cyclo-pent-1-ene.
| S-EPMC2977783 | biostudies-literature
Unknown (±)-1,2-Bis(N'-benzoyl-thio-ureido)cyclo-hexa-ne.
| S-EPMC3089146 | biostudies-literature