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Room-temperature C-H arylation: merger of Pd-catalyzed C-H functionalization and visible-light photocatalysis.

ABSTRACT: This communication describes the development of a room-temperature ligand-directed C-H arylation reaction using aryldiazonium salts. This was achieved by the successful merger of palladium-catalyzed C-H functionalization and visible-light photoredox catalysis. The new method is general for a variety of directing groups and tolerates many common functional groups.

SUBMITTER: Kalyani D

PROVIDER: S-EPMC3222896 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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Room-temperature C-H arylation: merger of Pd-catalyzed C-H functionalization and visible-light photocatalysis.

Kalyani Dipannita D McMurtrey Kate B KB Neufeldt Sharon R SR Sanford Melanie S MS

Journal of the American Chemical Society 20111102 46

This communication describes the development of a room-temperature ligand-directed C-H arylation reaction using aryldiazonium salts. This was achieved by the successful merger of palladium-catalyzed C-H functionalization and visible-light photoredox catalysis. The new method is general for a variety of directing groups and tolerates many common functional groups. ...[more]

PMID: 22047138

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