Unknown

Dataset Information

0

1-(2,4-Dichloro-benz-yl)pyridinium bis-(2-sulfanyl-idene-1,3-dithiole-4,5-dithiol-ato-?S,S')nickelate(III).

ABSTRACT: In the title compound, (C(12)H(10)Cl(2)N)[Ni(C(3)S(5))(2)], the Ni(III) atom is chelated by two bidentate 2-sulfanyl-idene-1,3-dithiole-4,5-dithiol-ate (dmit) dianions and shows a distorted square-planar geometry. The two dmit ligands are twisted with respect to each other by 3.21?(2)°. In the cation, the two aromatic groups linked by the methyl-ene bridging group form a dihedral angle of 68.09?(2)°. S?S [3.6212?(11) and 3.5573?(9)?Å] and Ni?S [3.566?(2)Å] inter-actions influence the arrangement of the anions in the crystal.

SUBMITTER: Liu GX 

PROVIDER: S-EPMC3238590 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

1-(2,4-Dichloro-benz-yl)pyridinium bis-(2-sulfanyl-idene-1,3-dithiole-4,5-dithiol-ato-κS,S')nickelate(III).

Liu Guang-Xiang GX  

Acta crystallographica. Section E, Structure reports online 20111102 Pt 12

In the title compound, (C(12)H(10)Cl(2)N)[Ni(C(3)S(5))(2)], the Ni(III) atom is chelated by two bidentate 2-sulfanyl-idene-1,3-dithiole-4,5-dithiol-ate (dmit) dianions and shows a distorted square-planar geometry. The two dmit ligands are twisted with respect to each other by 3.21 (2)°. In the cation, the two aromatic groups linked by the methyl-ene bridging group form a dihedral angle of 68.09 (2)°. S⋯S [3.6212 (11) and 3.5573 (9) Å] and Ni⋯S [3.566 (2)Å] inter-actions influence the arrangement  ...[more]

Similar Datasets

Unknown 1-(3,4-Dichloro-benz-yl)pyridinium bis-(2-sulfanyl-idene-1,3-dithiole-4,5-dithiol-ato-κS,S')nickelate(III).
| S-EPMC3246987 | biostudies-literature
Unknown 4-Cyano-1-(4-nitro-benz-yl)pyridinium bis-(2-thioxo-1,3-dithiole-4,5-dithiol-ato-?S,S)nickelate(III).
| S-EPMC2983398 | biostudies-literature
Unknown 1-(4-Bromo-2-fluoro-benz-yl)pyridinium bis-(2-thioxo-1,3-dithiole-4,5-dithiol-ato)nickelate(III).
| S-EPMC3009307 | biostudies-other
Unknown 1-(2-Fluoro-benz-yl)quinolinium bis-(2-sulfanylidene-1,3-dithiole-4,5-dithiol-ato-?S,S')nickelate(III).
| S-EPMC3089345 | biostudies-literature
Unknown 1-(4-Iodo-benz-yl)-3-methyl-pyridinium bis-(benzene-1,2-dithiol-ato)nickelate(III).
| S-EPMC3247529 | biostudies-literature
Unknown 1-(4-Cyano-benz-yl)-3,5-dimethyl-pyridinium bis-(benzene-1,2-dithiol-ato)nickelate(III).
| S-EPMC3051972 | biostudies-literature
Unknown Bis[1-(4-chloro-benz-yl)pyridinium] bis-(1,2,5-thia-diazole-3,4-dithiol-ato)nickelate(II).
| S-EPMC3212200 | biostudies-literature
Unknown Bis[1-(3-cyano-benz-yl)pyridinium] bis-(1,2-dicyano-ethene-1,2-dithiol-ato)nickelate(II).
| S-EPMC3050285 | biostudies-literature
Unknown Bis[1-(2,6-dichloro-benz-yl)-3-methyl-pyrazin-1-ium] bis-(maleonitrile-dithiol-ato)nickelate(II).
| S-EPMC2959589 | biostudies-literature
Unknown Bis[(E)-1-(3,4-dichloro-benzyl-idene-amino)-4-methyl-pyridinium] bis-(maleonitrile-dithiol-ato)nickelate(II).
| S-EPMC2968142 | biostudies-literature