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1-(2,4-Dichloro-benz-yl)pyridinium bis-(2-sulfanyl-idene-1,3-dithiole-4,5-dithiol-ato-?S,S')nickelate(III).

ABSTRACT: In the title compound, (C(12)H(10)Cl(2)N)[Ni(C(3)S(5))(2)], the Ni(III) atom is chelated by two bidentate 2-sulfanyl-idene-1,3-dithiole-4,5-dithiol-ate (dmit) dianions and shows a distorted square-planar geometry. The two dmit ligands are twisted with respect to each other by 3.21?(2)°. In the cation, the two aromatic groups linked by the methyl-ene bridging group form a dihedral angle of 68.09?(2)°. S?S [3.6212?(11) and 3.5573?(9)?Å] and Ni?S [3.566?(2)Å] inter-actions influence the arrangement of the anions in the crystal.

SUBMITTER: Liu GX

PROVIDER: S-EPMC3238590 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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1-(2,4-Dichloro-benz-yl)pyridinium bis-(2-sulfanyl-idene-1,3-dithiole-4,5-dithiol-ato-κS,S')nickelate(III).

Liu Guang-Xiang GX

Acta crystallographica. Section E, Structure reports online 20111102 Pt 12

In the title compound, (C(12)H(10)Cl(2)N)[Ni(C(3)S(5))(2)], the Ni(III) atom is chelated by two bidentate 2-sulfanyl-idene-1,3-dithiole-4,5-dithiol-ate (dmit) dianions and shows a distorted square-planar geometry. The two dmit ligands are twisted with respect to each other by 3.21 (2)°. In the cation, the two aromatic groups linked by the methyl-ene bridging group form a dihedral angle of 68.09 (2)°. S⋯S [3.6212 (11) and 3.5573 (9) Å] and Ni⋯S [3.566 (2)Å] inter-actions influence the arrangement ...[more]

PMID: 22199481

Similar Datasets

1-(3,4-Dichloro-benz-yl)pyridinium bis-(2-sulfanyl-idene-1,3-dithiole-4,5-dithiol-ato-κS,S')nickelate(III).

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