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Catena-Poly[[diaqua-lithium]-?-[rac-cis-(2-carb-oxy-cyclo-hexane-1-carboxyl-ato-?O:O]].

ABSTRACT: In the structure of the title compound, [Li(C(8)H(11)O(4))(H(2)O)(2)](n), the distorted tetra-hadral LiO(4) coordination sphere comprises two water mol-ecules and two carboxyl O-atom donors from separate bridging cis-2-carb-oxy-cyclo-hexane-1-carboxyl-ate monoanions [Li-O = 1.887?(4)-1.946?(3)?Å], giving chain substructures which extend along [010]. Water-water and water-carboxyl O-H?O hydrogen bonds stabilize these chain structures and provide inter-chain links, resulting in a two-dimensional layered structure extending parallel to (100).

SUBMITTER: Smith G

PROVIDER: S-EPMC3238593 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[diaqua-lithium]-μ-[rac-cis-(2-carb-oxy-cyclo-hexane-1-carboxyl-ato-κO:O]].

Smith Graham G Wermuth Urs D UD Williams Michael L ML

Acta crystallographica. Section E, Structure reports online 20111105 Pt 12

In the structure of the title compound, [Li(C(8)H(11)O(4))(H(2)O)(2)](n), the distorted tetra-hadral LiO(4) coordination sphere comprises two water mol-ecules and two carboxyl O-atom donors from separate bridging cis-2-carb-oxy-cyclo-hexane-1-carboxyl-ate monoanions [Li-O = 1.887 (4)-1.946 (3) Å], giving chain substructures which extend along [010]. Water-water and water-carboxyl O-H⋯O hydrogen bonds stabilize these chain structures and provide inter-chain links, resulting in a two-dimensional l ...[more]

PMID: 22199484

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