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Poly[tetra-aquadi-?(4)-oxalato-potassium-ytterbium(III)].


ABSTRACT: In the title compound, [KYb(C(2)O(4))(2)(H(2)O)(4)](n), the Yb(III) ion lies on a site of [Formula: see text] symmetry in a dodeca-hedral environment defined by eight O atoms from four oxalate ligands. The K atom lies on a different [Formula: see text] axis and is coordinated by four O atoms from four oxalate ligands and four water O atoms. The oxalate ligand has an inversion center at the mid-point of the C-C bond. The metal ions are linked by the oxalate ligands into a three-dimensional framework. O-H?O hydrogen bonding is present in the crystal structure.

SUBMITTER: Zhang FM 

PROVIDER: S-EPMC3238636 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Poly[tetra-aquadi-μ(4)-oxalato-potassium-ytterbium(III)].

Zhang Feng-Ming FM   Hou Guang-Feng GF   Yan Peng-Fei PF   Li Guang-Ming GM  

Acta crystallographica. Section E, Structure reports online 20111109 Pt 12


In the title compound, [KYb(C(2)O(4))(2)(H(2)O)(4)](n), the Yb(III) ion lies on a site of [Formula: see text] symmetry in a dodeca-hedral environment defined by eight O atoms from four oxalate ligands. The K atom lies on a different [Formula: see text] axis and is coordinated by four O atoms from four oxalate ligands and four water O atoms. The oxalate ligand has an inversion center at the mid-point of the C-C bond. The metal ions are linked by the oxalate ligands into a three-dimensional framew  ...[more]

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