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Monoclinic form of (Z)-1-ferrocenyl-3-(3-hy-droxy-anilino)but-2-en-1-one.

ABSTRACT: The title compound, [Fe(C(5)H(5))(C(15)H(14)NO(2))], is a monoclinic polymorph of the previously reported triclinic form [Shi et al. (2006 ?). Acta Cryst. C62, m407-m410]. The polymorphs feature the same strong intra-molecular N-H?O=C hydrogen bonds, but show different packing modes. The mol-ecules in the monoclinic form associate into double chains via O-H?O=C and (Cp)C-H?O-H inter-actions.

SUBMITTER: Zhou J

PROVIDER: S-EPMC3238667 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Monoclinic form of (Z)-1-ferrocenyl-3-(3-hy-droxy-anilino)but-2-en-1-one.

Zhou Jie J Ji Yuan-Yuan YY Shi Yao-Cheng YC Shen Wen-Bin WB Yuan Li-Min LM

Acta crystallographica. Section E, Structure reports online 20111116 Pt 12

The title compound, [Fe(C(5)H(5))(C(15)H(14)NO(2))], is a monoclinic polymorph of the previously reported triclinic form [Shi et al. (2006 ▶). Acta Cryst. C62, m407-m410]. The polymorphs feature the same strong intra-molecular N-H⋯O=C hydrogen bonds, but show different packing modes. The mol-ecules in the monoclinic form associate into double chains via O-H⋯O=C and (Cp)C-H⋯O-H inter-actions. ...[more]

PMID: 22199558

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