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Ethyl (Z)-4-ferrocenyl-2-(4-hy-droxy-anilino)-4-oxobutenoate.

ABSTRACT: In the title compound, [Fe(C(5)H(5))(C(17)H(16)NO(4))], the O=C-C=C-N mean plane is twisted with respect to the mean planes of the benzene and substituted cyclo-penta-dienyl rings by 44.2?(2) and 13.8?(3)°, respectively. Furthermore, the O=C-C=C-N mean plane and the O=C-O(ester) plane make a dihedral angle of 55.5?(6)°. Consistent with this large dihedral angle, the linking C-C bond [1.507?(6)?Å] does not show any (delocalized) double-bond character.

SUBMITTER: Zhu BB

PROVIDER: S-EPMC3238666 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Ethyl (Z)-4-ferrocenyl-2-(4-hy-droxy-anilino)-4-oxobutenoate.

Zhu Bei-Bei BB Shi Yao-Cheng YC Zhang Feng-Min FM Yuan Li-Min LM Li Qian-Kun QK

Acta crystallographica. Section E, Structure reports online 20111116 Pt 12

In the title compound, [Fe(C(5)H(5))(C(17)H(16)NO(4))], the O=C-C=C-N mean plane is twisted with respect to the mean planes of the benzene and substituted cyclo-penta-dienyl rings by 44.2 (2) and 13.8 (3)°, respectively. Furthermore, the O=C-C=C-N mean plane and the O=C-O(ester) plane make a dihedral angle of 55.5 (6)°. Consistent with this large dihedral angle, the linking C-C bond [1.507 (6) Å] does not show any (delocalized) double-bond character. ...[more]

PMID: 22199557

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