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Aqua-(4,4'-dimethyl-2,2'-bipyridine-?N,N')(nitrato-?O)(nitrato-?O,O')zinc.

ABSTRACT: In the title compound, [Zn(NO(3))(2)(C(12)H(12)N(2))(H(2)O)], the Zn(II) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a chelating 4,4'-dimethyl-2,2'-bipyridine ligand, one water O atom, one O atom from a monodentate nitrate anion and two O atoms from a chelating nitrate anion. In the crystal, there are aromatic ?-? contacts between the pyridine rings [centroid-centroid distances = 3.9577?(13)?Å] and inter-molecular O-H?O and C-H?O hydrogen bonds.

SUBMITTER: Shirvan SA

PROVIDER: S-EPMC3238756 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Aqua-(4,4'-dimethyl-2,2'-bipyridine-κN,N')(nitrato-κO)(nitrato-κO,O')zinc.

Shirvan Sadif A SA Haydari Dezfuli Sara S

Acta crystallographica. Section E, Structure reports online 20111130 Pt 12

In the title compound, [Zn(NO(3))(2)(C(12)H(12)N(2))(H(2)O)], the Zn(II) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a chelating 4,4'-dimethyl-2,2'-bipyridine ligand, one water O atom, one O atom from a monodentate nitrate anion and two O atoms from a chelating nitrate anion. In the crystal, there are aromatic π-π contacts between the pyridine rings [centroid-centroid distances = 3.9577 (13) Å] and inter-molecular O-H⋯O and C-H⋯O hydrogen bonds. ...[more]

PMID: 22199633

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2,2'-Dimethyl-4,4'-bipyridine.

Project description:In the crystal structure of the title compound, C(12)H(12)N(2), the mol-ecule is twisted around the central C-C bond, with a dihedral angle of 8.32 (5)° between the mean planes of the pyridyl rings. The crystal structure is stabilized by arene stacking inter-actions, with a distance of 3.81 (1) Å between the ring centroids.

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Project description:The asymmetric unit of the title compound, [ZnBr(2)(C(12)H(12)N(2))], contains two half-mol-ecules; both are completed by crystallographic twofold axes running through the Zn(II) atoms which are coordinated by an N,N'-bidentate 4,4'-dimethyl-2,2'-bipyridine ligand and two Br(-) ions, resulting in distorted ZnN(2)Br(2) tetra-hedral coordination geometries. In the crystal, C-H?Br inter-actions link the mol-ecules.

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(4,4'-Dimethyl-2,2'-bipyridine-κN,N')diiodidomercury(II).

Project description:In the mol-ecule of the title compound, [HgI(2)(C(12)H(12)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from the 4,4'-dimethyl-2,2'-bipyridine ligand and by two I atoms. There is a π-π contact between the pyridine rings [centroid-centroid distance = 3.775 (6) Å].

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Bis(acetato-κ(2)O,O')(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')-zinc.

Project description:The mol-ecular structure of the title compound, [Zn(CH(3)COO)(2)(C(12)H(12)N(2))], consists of isolated mol-ecules bis-ected by a twofold rotation axis which goes through the Zn(II) cation and halves the organic base through the central C-C bond. The Zn(II) ion is coordinated by two N atoms from one mol-ecule of the aromatic base and four O atoms from two bidentate, symmetry-related acetate anions, which coordinate asym-metrically [Zn-O distances of 2.058 (2) and 2.362 (3) Å], while the two Zn-N bond distances are equal as imposed by symmetry [2.079 (2) Å]. The crystal structure is supported by a number of weak C-H⋯O inter-actions and C-H⋯π contacts, with no π-π inter-actions present, mainly hindered by the substituent methyl groups and the relative mol-ecular orientation. The result is a three-dimensional structure in which each mol-ecule is linked to eight different neighbors.

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(4,4'-Dimethyl-2,2'-bipyridine-?N,N')(dimethyl sulfoxide-?O)diiodidocadmium(II).

Project description:In the title compound, [CdI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) cation is coordinated by two N atoms from a dimethyl-bipyridine ligand, one O atom from a dimethyl sulfoxide mol-ecule and two I(-) anions in a distorted trigonal-bipyramidal geometry. Intra-molecular C-H?O hydrogen bonding and inter-molecular ?-? stacking between parallel pyridine rings [centroid-centroid distance = 3.658?(3)?Å] are present in the crystal structure.

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(4,4'-Dimethyl-2,2'-bipyridine-?N,N')(dimethyl sulfoxide-?O)diiodidozinc(II).

Project description:In the title compound, [ZnI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Zn(II) ion is coordinated by two N atoms from a 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethyl sulfoxide mol-ecule and two I atoms in a distorted trigonal-bipyramidal geometry. Intra-molecular C-H?O hydrogen bonds and inter-molecular ?-? stacking inter-actions between the pyridine rings [centroid-centroid distances = 3.637?(4) and 3.818?(4)?Å] are present in the crystal structure.

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