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Dichloridobis(4-methyl-3,5-diphenyl-1H-pyrazole-?N)copper(II).

ABSTRACT: The asymmetric unit of the title compound, [CuCl(2)(C(16)H(14)N(2))(2)], comprises half of the complex. The Cu(II) atom lies on a crystallographic twofold rotation axis and shows a significantly distorted tetra-hedral coordination geometry. The dihedral angle between the phenyl rings is 74.3?(2)°. The crystal structure is stabilized by inter-molecular ?-? inter-actions [centroid-centroid distances = 3.635?(2)-3.803?(3)?Å].

SUBMITTER: Hossaini Sadr M

PROVIDER: S-EPMC3238775 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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Dichloridobis(4-methyl-3,5-diphenyl-1H-pyrazole-κN)copper(II).

Hossaini Sadr Moayad M Soltani Behzad B

Acta crystallographica. Section E, Structure reports online 20111130 Pt 12

The asymmetric unit of the title compound, [CuCl(2)(C(16)H(14)N(2))(2)], comprises half of the complex. The Cu(II) atom lies on a crystallographic twofold rotation axis and shows a significantly distorted tetra-hedral coordination geometry. The dihedral angle between the phenyl rings is 74.3 (2)°. The crystal structure is stabilized by inter-molecular π-π inter-actions [centroid-centroid distances = 3.635 (2)-3.803 (3) Å]. ...[more]

PMID: 22199652

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