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Dichloridobis(3,5-dimethyl-1H-pyrazol-4-amine-κN)cobalt(II).

ABSTRACT: In the title compound, [CoCl(2)(C(5)H(9)N(3))(2)], the Co(II) atom adopts a slightly distorted tetra-hedral coordination geometry provided by two chloride anions and two N atoms from the organic ligands. The dihedral angle between the pyrazole rings is 85.91 (10)°. In the crystal structure, mol-ecules are linked into a three-dimensional network by inter-molecular N-H⋯N and N-H⋯Cl hydrogen-bonding inter-actions.

SUBMITTER: Cai XW

PROVIDER: S-EPMC2961935 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Dichloridobis(3,5-dimethyl-1H-pyrazol-4-amine-κN)cobalt(II).

Cai Xing-Wei XW Zhao Yu-Yuan YY Han Guang-Fan GF

Acta crystallographica. Section E, Structure reports online 20080709 Pt 8

In the title compound, [CoCl(2)(C(5)H(9)N(3))(2)], the Co(II) atom adopts a slightly distorted tetra-hedral coordination geometry provided by two chloride anions and two N atoms from the organic ligands. The dihedral angle between the pyrazole rings is 85.91 (10)°. In the crystal structure, mol-ecules are linked into a three-dimensional network by inter-molecular N-H⋯N and N-H⋯Cl hydrogen-bonding inter-actions. ...[more]

PMID: 21203006

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