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N,N'-Bis(pyridin-2-yl)benzene-1,4-diamine-naphthalene (2/1).

ABSTRACT: The asymmetric unit of the title compound, C(10)H(8)·2C(16)H(14)N(4), consists of one mol-ecule of N,N'-bis-(pyridin-2-yl)benzene-1,4-diamine (PDAB) and one half of the centrosymmetric naphthalene mol-ecule. The PDAB mol-ecule adopts a non-planar conformation with an E configuration at the two partially double exo C N bonds of the 2-pyridyl-amine units. In the crystal, N-H⋯N hydrogen bonds between the PDAB mol-ecules generate a cyclic R(2) (2)(8) motif, leading to the formation of PDAB tapes extending along [100]. The tapes are arranged into (010) layers and the naphthalene mol-ecules are enclosed in cavities formed between the PDAB layers.

SUBMITTER: Wicher B

PROVIDER: S-EPMC3238953 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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N,N'-Bis(pyridin-2-yl)benzene-1,4-diamine-naphthalene (2/1).

Wicher Barbara B Gdaniec Maria M

Acta crystallographica. Section E, Structure reports online 20111112 Pt 12

The asymmetric unit of the title compound, C(10)H(8)·2C(16)H(14)N(4), consists of one mol-ecule of N,N'-bis-(pyridin-2-yl)benzene-1,4-diamine (PDAB) and one half of the centrosymmetric naphthalene mol-ecule. The PDAB mol-ecule adopts a non-planar conformation with an E configuration at the two partially double exo C N bonds of the 2-pyridyl-amine units. In the crystal, N-H⋯N hydrogen bonds between the PDAB mol-ecules generate a cyclic R(2) (2)(8) motif, leading to the formation of PDAB tapes ext ...[more]

PMID: 22199802

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