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Catena-Poly[[bis-(nitrato-?O)cadmium]bis-[?-1,4-bis-(pyridin-3-yl-meth-oxy)benzene-?N:N']].

ABSTRACT: In the title compound, [Cd(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the six-coordinated Cd(II) ion is located on an inversion center and has a distorted octa-hedral environment defined by four N atoms from four 1,4-bis-(pyridin-3-ylmeth-oxy)benzene ligands and two O atoms from two nitrate anions. The ligands link the Cd(II) ions into a ribbon-like structure running along [201]. One O atom of the nitrate anion is disordered over two positions with site-occupancy factors of 0.59?(2) and 0.41?(2).

SUBMITTER: Zhang S 

PROVIDER: S-EPMC3200741 | biostudies-literature | 2011 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-(nitrato-κO)cadmium]bis-[μ-1,4-bis-(pyridin-3-yl-meth-oxy)benzene-κN:N']].

Zhang Shuang S   Yu Ying-Hui YH   Liu Ying Y   Hou Guang-Feng GF   Gao Jin-Sheng JS  

Acta crystallographica. Section E, Structure reports online 20110817 Pt 9

In the title compound, [Cd(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the six-coordinated Cd(II) ion is located on an inversion center and has a distorted octa-hedral environment defined by four N atoms from four 1,4-bis-(pyridin-3-ylmeth-oxy)benzene ligands and two O atoms from two nitrate anions. The ligands link the Cd(II) ions into a ribbon-like structure running along [201]. One O atom of the nitrate anion is disordered over two positions with site-occupancy factors of 0.59 (2) and 0.41 (2). ...[more]

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